51335-91-2

Basic information

• Product Name: Ethanone, 1-[5-(4-methylphenyl)-2-thienyl]-
• CAS NO: 51335-91-2
• Molecular Formula: C13H12OS
• Molecular Weight: 216.304
• Mol File: 51335-91-2.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[5-(4-methylphenyl)-2-thienyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[5-(4-methylphenyl)-2-thienyl]-(51335-91-2)
• EPA Substance Registry System: Ethanone, 1-[5-(4-methylphenyl)-2-thienyl]-(51335-91-2)

Safety Data

• Hazardous Substances Data: 51335-91-2(Hazardous Substances Data)

Upstream product

• 88-15-3 2-Acetylthiophene 
• 2028-84-4 p-methylbenzenediazonium chloride 
• 624-31-7 4-tolyl iodide 
• 106-38-7 para-bromotoluene 
• 206551-43-1 (5-acetylthiophen-2-yl)boronic acid 
• 106-43-4 para-chlorotoluene 
• 30955-94-3 2-acetyl-5-iodothiophene 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 5370-25-2 2-Acetyl-5-bromothiophene 
• 106-49-0 p-toluidine 
• 5720-05-8 4-methylphenylboronic acid 
• 16939-04-1 2-p-tolylthiophene 
• 75-36-5 acetyl chloride 

Downstream Products

• 1083304-46-4 C₂₁H₁₄ClNO₂S 
• 1083376-46-8 C₂₁H₁₄BrNO₂S 
• 93599-09-8 2-Methyl-2-[1-(5-p-tolyl-thiophen-2-yl)-eth-(E)-ylideneaminooxy]-propionic acid ethyl ester 
• 93599-08-7 2-[1-(5-p-Tolyl-thiophen-2-yl)-eth-(E)-ylideneaminooxy]-propionic acid ethyl ester 
• 93599-07-6 [1-(5-p-Tolyl-thiophen-2-yl)-eth-(E)-ylideneaminooxy]-acetic acid ethyl ester 
• 93599-03-2 1-(5-p-Tolyl-thiophen-2-yl)-ethanone O-(2-diethylamino-ethyl)-oxime 
• 93599-02-1 1-(5-p-Tolyl-thiophen-2-yl)-ethanone O-propyl-oxime 
• 93599-01-0 1-(5-p-Tolyl-thiophen-2-yl)-ethanone O-ethyl-oxime 
• 93599-00-9 O-Methyl-5-p-tolylthiophene-2-acetoxime 
• 93599-31-6 5-p-Tolyl-2-acetylthiophene oxime 
• 93599-10-1 O-Benzyl-5-p-tolylthiophene-2-acetoxime 
• 105924-49-0 2-bromo-1-(5-p-tolyl-[2]thienyl)-ethanone 
• 40808-21-7 5-(4-methylphenyl)thiophene-2-carboxylic acid 
• 854867-55-3 2-(5-p-tolyl-[2]thienyl)-quinoline-4-carboxylic acid 

Relevant articles and documents

New benzimidazolium N-heterocyclic carbene precursors and their related Pd-NHC complex PEPPSI-type: Synthesis, structures, DFT calculations, biological activity, docking study, and catalytic application in the direct arylation

New benzhydryl-5,6-dimethyl-(3-methylbenzyl)benzimidazolium salt as N-heterocyclic carbene precursors and their related new Pd-NHC complex PEPPSI-type with the general formula [PdBr2(NHC)(pyridine)] were prepared and theoretically studied. Quan

Synthesis, characterization and catalytic activity of PEPPSI-type palladium–NHC complexes

Eight benzimidazolium salts (2a–h) with two nitrogen atoms substituted by various alkyl groups have been synthesized in high yields. The benzimidazolium salts were readily converted into the corresponding PEPPSI-type palladium–NHC complexes (PEPPSI = pyridine-enhanced precatalyst preparation, stabilization, and initiation) (3a–h). The structures of all compounds were characterized by 1H NMR, 13C NMR, and IR spectroscopy as well as by elemental analysis techniques, which support the proposed structures. The catalytic activity of the PEPPSI-type palladium–NHC complexes was evaluated with respect to the direct C5-arylation of 2-substituted heteroaryl derivatives (thiophene, furan and thiazole) with various aryl bromides. This arylation occurs efficiently and selectively at the C5-position of the 2-substituted thiophene, furan and thiazole derivatives.

Synthesis, structures, DFT calculations, and catalytic application in the direct arylation of five-membered heteroarenes with aryl bromides of novel palladium-N-heterocyclic carbene PEPPSI-type complexes

A new series of Pd-catalysts based on an N-heterocyclic carbene PEPPSI-type ligand (PEPPSI = pyridine enhanced precatalyst preparation stabilization and initiation) with the general formula [Pd(ii)Br2(NHC)(pyridine)] was synthesized and fully characterize