51343-26-1

Basic information

• Product Name: 6-Oxa-3-silabicyclo[3.1.0]hexane, 3,3-diphenyl-
• CAS NO: 51343-26-1
• Molecular Formula: C16H16OSi
• Molecular Weight: 252.388
• Mol File: 51343-26-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 6-Oxa-3-silabicyclo[3.1.0]hexane, 3,3-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Oxa-3-silabicyclo[3.1.0]hexane, 3,3-diphenyl-(51343-26-1)
• EPA Substance Registry System: 6-Oxa-3-silabicyclo[3.1.0]hexane, 3,3-diphenyl-(51343-26-1)

Safety Data

• Hazardous Substances Data: 51343-26-1(Hazardous Substances Data)

Upstream product

• 34106-93-9 1,1-diphenylsilacyclopent-3-ene 

Downstream Products

• 405516-88-3 1,1-diphenyl-2,3-dihydro-1H-silol-3-ol 
• 71404-32-5 1,1-diphenylsilacyclopent-2-en-4-ol 
• 459850-60-3 1,1-diphenyl-2,3-dihydro-1H-silol-3-ol 
• 512-63-0 1,1,3,3,5,5-hexaphenylcyclotrisiloxane 
• 106-99-0 buta-1,3-diene 
• 18843-79-3 polyphenylsiloxane 
• 51343-52-3 4-bromo-1,1-diphenyl-silolan-3-ol 
• 51343-51-2 4-chloro-1,1-diphenyl-silolan-3-ol 

Relevant articles and documents

Catalytic enantioselective isomerization of silacyclopentene oxides: New strategy for stereocontrolled assembly of acyclic polyols

A versatile precursor for the assembly of a range of polyol-containing fragment is the silacyclic alcohol 2 that results from the highly enantioselective, calalytic isomerization of diphenylsilacyclopentene oxide (1). The use of this precursor is illustrated with the efficient and highly diastereoselective assembly of acyclic tetraol motifs.

Construction of 2,3- and 3,4-functionalized silacyclopentanes: Synthesis of 6-aza-2,2-diphenyl-2-silabicyclo[3.1.0]hexane and 6-aza-3,3-diphenyl-3- silabicyclo[3.1.0]hexane derivatives

The synthesis of five azasilabicyclo[3.1.0]hexanes containing an aziridine function in the α- or the β- position of the silicon atom is described. These bicyclic heterocompounds differ by the various substituents (H, Me, CO2Et, CPh3)