51830-12-7

Basic information

• Product Name: 2-Propenoicacid,3-(3-methyloxiranyl)-,methylester(9CI)
• Synonyms: 2-Propenoicacid,3-(3-methyloxiranyl)-,methylester(9CI);(E)-methyl 3-(3-methyloxiran-2-yl)acrylate
• CAS NO: 51830-12-7
• Molecular Formula: C₇H₁₀O₃
• Molecular Weight: 142.15
• Product Categories: EPOXYDE
• Mol File: 51830-12-7.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Propenoicacid,3-(3-methyloxiranyl)-,methylester(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoicacid,3-(3-methyloxiranyl)-,methylester(9CI)(51830-12-7)
• EPA Substance Registry System: 2-Propenoicacid,3-(3-methyloxiranyl)-,methylester(9CI)(51830-12-7)

Safety Data

• Hazardous Substances Data: 51830-12-7(Hazardous Substances Data)

Upstream product

• 1515-80-6 sorbic acid methyl ester 
• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 

Downstream Products

• 118355-47-8 (E)-4-Benzenesulfonylamino-5-hydroxy-hex-2-enoic acid methyl ester 
• 139622-42-7 (+/-) methyl (4,5)-anti-5-hydroxy-4-(4'-methylphenoxy)-(2E)-hexenoate 
• 139622-43-8 (+/-) methyl (4,5)-anti-5-hydroxy-4-(2'-hydroxy-5'-methylphenyl)-(2E)-hexenoate 
• 139622-48-3 (+/-) methyl (4,5)-anti-5-hydroxy-4-(2',4',6'-trimethoxyphenyl)-(2E)-hexenoate 
• 139622-45-0 methyl (4,5)-anti-4-(3',4'-dimethoxyphenyl)-5-hydroxy-2(E)-hexenoate 
• 148826-21-5 (+/-) methyl (2,5)-anti-5-hydroxy-2-(2',4',5'-trimethoxyphenyl)-(3E)-hexenoate 
• 148826-19-1 (+/-) methyl (4,5)-anti-5-hydroxy-4-(2',4',5'-trimethoxyphenyl)-(2E)-hexenoate 
• 139622-49-4 (+/-) methyl (4,5)-anti-5-hydroxy-4-thiophenoxy-(2E)-hexenoate 
• 139622-44-9 rac-(2E,4S,5S)-methyl 5-hydroxy-4-(4-methoxyphenyl)-hex-2-enoate 
• 139622-39-2 (+/-) methyl (4,5)-anti-5-hydroxy-4-(p-methoxyphenoxy)-(2E)-hexenoate 
• 139622-41-6 (+/-) methyl (4,5)-anti-5-hydroxy-4-(5'-hydroxy-2'-methoxyphenyl)-(2E)-hexenoate 
• 139622-40-5 (+/-) methyl (4,5)-anti-5-hydroxy-4-(2'-hydroxy-5'-methoxyphenyl)-(2E)-hexenoate 
• 107686-10-2 Benzoic acid (E)-(R)-1-((S)-1-hydroxy-ethyl)-3-methoxycarbonyl-allyl ester 
• 107686-11-3 Benzoic acid (E)-(1R,2S)-2-hydroxy-4-methoxycarbonyl-1-methyl-but-3-enyl ester 

Relevant articles and documents

Chloroperoxidase-catalyzed oxidation of conjugated dienoic esters

The chloroperoxidase (CPO)-catalyzed oxidations of dienes conjugated to an ester group were studied using tert-butyl hydroperoxide as the terminal oxidant.

Ruthenium-catalysed reductive cleavage of allylic esters with formic acid and triethylamine. Application to short-step synthesis of α-hydroxy acids

Ruthenium-catalysed reductive cleavage reactions of allylic carboxylates and carbonates with formic acid and triethylamine to give olefins were explored.As an application of the ruthenium-catalysed processes, a new synthetic route to α-hydroxy acids has been discovered.The reductive cleavage of allylic esters is considered to proceed through ?-allylruthenium intermediates. Key words: Ruthenium; Catalysis; Reductive cleavage; Allyl; Formic acid

Cobalt(II) complex catalysed epoxidation with molecular oxygen

Cobalt(II) complexes 1 or 2, catalyses the epoxidation of alkenes in the presence of molecular oxygen and 2-methylpropanal in high yields.