52755-39-2

Basic information

• Product Name: Benzenemethanol, a-(1E)-1-propenyl-
• CAS NO: 52755-39-2
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 52755-39-2.mol
• Article Data: 56

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1E)-1-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1E)-1-propenyl-(52755-39-2)
• EPA Substance Registry System: Benzenemethanol, a-(1E)-1-propenyl-(52755-39-2)

Safety Data

• Hazardous Substances Data: 52755-39-2(Hazardous Substances Data)

Upstream product

• 495-41-0 1-phenylbut-2-en-1-one 
• 100-52-7 benzaldehyde 
• 107-18-6 allyl alcohol 
• 100-58-3 phenylmagnesium bromide 
• 123-73-9 crotonaldehyde 
• 135787-84-7 2-(1-Bromo-ethyl)-3-phenyl-oxirane 
• 100-59-4 phenylmagnesium chloride 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 1730-25-2 (E)-1-propenylmagnesium bromide 
• 13154-14-8 1-propenylmagnesium bromide 
• 108-86-1 bromobenzene 
• 123-73-9 trans-Crotonaldehyde 
• 14593-43-2 benzyl allyl ether 
• 32426-80-5 (Z)-((prop-1-en-1-yloxy)methyl)benzene 

Downstream Products

• 36004-04-3 ethyl (E)-1-phenylbut-1-en-3-ol 
• 105337-67-5 (E)-(3-ethoxybut-1-en-1-yl)benzene 
• 51801-01-5 1-phenylbut-2-en-1-yl acetate 
• 51801-01-5 (E)-1-acetoxy-1-phenyl-2-butene 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 
• 104-51-8 1-butylbenzene 
• 2344-70-9 1-phenyl-3-butanol 
• 1560-06-1 1-phenyl-2-butene 
• 614-14-2 1-Phenyl-1-butanol 
• 17488-65-2 4-phenylbut-3-en-2-ol 
• 67685-90-9 methyl 3-phenyl-1-methylpropyl ether 
• 19261-14-4 1-phenylbut-3-ene-1,2-diol 
• 699023-45-5 N-[1,3-dimethyl-2-(1-phenyl-but-2-enyloxy)-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene]-4-methyl-benzenesulfonamide 
• 6585-32-6 2-methylcyclopropyl phenyl ketone 

Relevant articles and documents

New γ-Halo-δ-lactones and δ-Hydroxy-γ-lactones with Strong Cytotoxic Activity

This paper presents the synthesis of γ-halo-δ-lactones, δ-iodo-γ-lactones and δ-hydroxy-γ-lactones from readily available organic substrates such as trans-crotonaldehyde and aryl bromides. Crystal structure analysis was carried out for lactones that were obtained in crystalline form. All halo-δ-lactones and δ-hydroxy-γ-lactones were highly cytotoxic against gastric cancer AGS cells with IC50 values in the range of 0.0006–0.0044 mM. Some lactones showed high bactericidal activity against E. coli ATCC 8739 and S. aureus ATCC 65389, which reduced the number of CFU/mL by 70–83% and 87% respectively.

Enantioselective Radical Carbocyanation of 1,3-Dienes via Photocatalytic Generation of Allylcopper Complexes

1,3-Dienes are readily available feedstocks that are widely used in the laboratory and industry. However, the potential of converting 1,3-dienes into value-Added products, especially chiral products, has not yet been fully exploited. By synergetic photoredox/copper catalysis, we achieve the first visible-light-induced, enantioselective carbocyanation of 1,3-dienes by using carboxylic acid derivatives and trimethylsilyl cyanide. Under mild and neutral conditions, a diverse range of chiral allyl cyanides are produced in generally good efficiency and with high enantioselectivity from bench-stable and user-safe chemicals. Moreover, preliminary results also confirm that this success can be expanded to 1,3-enynes and the four-component carbonylative carbocyanation of 1,3-dienes and 1,3-enynes.

A Pd-Catalyzed Site-Controlled Isomerization of Terminal Olefins

An effective Pd-catalyzed isomerization of olefins with 2-PyPPh2 as the ligand is described. A wide variety of trans-2-olefins bearing various functional groups can be obtained with high regio- A nd stereoselectivity under mild reaction conditions. The ligand is crucial for the reaction.