52913-19-6Relevant articles and documents
Carbazole-functionalized organic photosensitizer for dye-sensitized solar cells
Lee, Jeonghun,Im, Hunbae,Kim, Sukwon,Kim, Chulhee
, p. 1434 - 1442 (2015)
We designed and synthesized the photosensitive ?? -conjugated organic dyes (CB-1, CB-2 and CB-3) with the carbazole substituted triphenylamine moiety as an electron donor unit and the cyanoacetic acid moiety as an acceptor for the application as a photosensitizer of dye-sensitized solar cells. The dyes with two carbazole units connected to triphenylamine moiety (CB-2 and CB-3) showed enhanced electron donating property than the one with one carbazole moiety as an electron donor unit (CB-1), which resulted in longer absorption maximum wavelength, higher overall photon to current conversion efficiency and IPCE values. In particular, CB-3 showed an absorption maximum wavelength at 428 nm and overall solar-to-energy conversion efficiency of 7.58% at AM 1.5 illumination (100 mW.cm-2) without mask.
Pd-Catalyzed Vinylation of Aryl Halides with Inexpensive Organosilicon Reagents Under Mild Conditions
Yang, Chu-Ting,Han, Jun,Liu, Jun,Li, Yi,Zhang, Fan,Yu, Hai-Zhu,Hu, Sheng,Wang, Xiaolin
supporting information, p. 10324 - 10328 (2018/07/31)
Pd-catalyzed Hiyama vinylation reaction of non-activated aryl chlorides and bromides under mild conditions was developed. The use of efficient vinyl donors and electron-rich sterically hindered phosphine ligands was critical for the success of the reaction. The products of this transformation can be used for Am/Cm separation, an important challenge in nuclear fuel reprocessing. The substituent effect on Am/Cm separating selectivity was also achieved, which could contribute to the development of new chromatographic materials for the separation of Am and Cm.
Molecular Engineering of UV/Vis Light-Emitting Diode (LED)-Sensitive Donor–π–Acceptor-Type Sulfonium Salt Photoacid Generators: Design, Synthesis, and Study of Photochemical and Photophysical Properties
Wu, Xingyu,Jin, Ming,Xie, Jianchao,Malval, Jean-Pierre,Wan, Decheng
, p. 15783 - 15789 (2017/10/20)
A series of donor–π–acceptor-type sulfonium salt photoacid generators (PAGs) were designed and synthesized by systematically changing electron-donating groups, π-conjugated systems, electron-withdrawing groups, and the number of branches through molecular engineering. These PAGs can effectively decompose under UV/Vis irradiation from a light-emitting diode (LED) light source because of the matching absorption and emitting spectra of the LEDs. The absorption and acid-generation properties of these sulfonium salts were elucidated by UV/Vis spectroscopy and so forth. Results indicated that the PAG performance benefited from the introduction of strong electron-donating groups, specific π-conjugated structures, certain electron-withdrawing groups, or two-branched structures. Most sulfonium salts showed potential as photoinitiators under irradiation by a wide variety of UV and visible LEDs.
