53109-16-3

Basic information

• Product Name: Benzene, [(1E)-1-methyl-1-heptenyl]-
• CAS NO: 53109-16-3
• Molecular Formula: C14H20
• Molecular Weight: 188.313
• Mol File: 53109-16-3.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzene, [(1E)-1-methyl-1-heptenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1E)-1-methyl-1-heptenyl]-(53109-16-3)
• EPA Substance Registry System: Benzene, [(1E)-1-methyl-1-heptenyl]-(53109-16-3)

Safety Data

• Hazardous Substances Data: 53109-16-3(Hazardous Substances Data)

Upstream product

• 629-05-0 n-octyne 
• 28557-00-8 phenylzinc chloride 
• 66-25-1 hexanal 
• 98-86-2 acetophenone 
• 592-41-6 1-hexene 
• 536-74-3 phenylacetylene 
• 77855-71-1 (E)-octa-1,3-dien-2-ylbenzene 
• 109-72-8 n-butyllithium 
• 39171-59-0 (4-bromobut-2-en-2-yl)benzene 
• 54976-39-5 (E)-1-bromo-3-phenyl-2-butene 
• 54976-37-3 (Z)-3-phenyl-2-buten-1-ol 
• 945-93-7 ethyl (Z)-3-phenylbut-2-enoate 
• 80441-37-8 2-phenyloctan-2-ol 
• 111-25-1 1-bromo-hexane 

Downstream Products

• 777-22-0 2-phenyloctane 
• 570368-32-0 (2S)-2-methyl-2-phenylheptanal 
• 1298088-89-7 C₁₄H₂₀O 
• 1298088-90-0 C₁₄H₂₀O 
• 1298088-84-2 C₁₄H₂₀O 

Relevant articles and documents

An Atom-Economic and Stereospecific Access to Trisubstituted Olefins through Enyne Cross Metathesis Followed by 1,4-Hydrogenation

The combination of intermolecular enyne cross metathesis and subsequent 1,4-hydrogenation opens a stereocontrolled and atom-economic access to trisubstituted olefins. By investigating different combinations of functionalized alkyne and alkene substrates, we found that the outcome (yield, E / Z ratio) of the Grubbs II-catalyzed enyne cross-metathesis step depends on the substrate's structure, the amount of the alkene (used in excess), and the (optional) presence of ethylene. In any case, the 1,4-hydrogenation, catalyzed by 1,2-dimethoxybenzene-Cr(CO) 3, proceeds stereospecifically to yield exclusively the E -products from both the E- and Z- 1,3-diene intermediates obtained by metathesis. A rather broad scope and functional group compatibility of the method is demonstrated by means of 15 examples.

Enantioselective synthesis of all-carbon quaternary stereogenic centers via copper-catalyzed asymmetric allylic alkylation of (Z)-allyl bromides with organolithium reagents

A copper/phosphoramidite catalyzed asymmetric allylic alkylation of Z trisubstituted allyl bromides with organolithium reagents is reported. The reaction affords all-carbon quaternary stereogenic centers in high yields and very good regio- and enantiosele

The thermofluoric behavior of poly(fluorenetolyldiphenylamine)-oxadiazole pair in a polymer matrix

Under UV irradiation, 1,4-bis(5-(4-octan-2-ylphenyl)-1,3,4-oxadiazol-2-yl) naphthalene (NOXD) and poly(fluorenetolyldiphenylamine) (PFT) are blue light emissive in solid film. When NOXD and PFT were blended to form a neat thin-film, yellowish exciplex emi