532-65-0 Usage
Description
ar-Turmerone is a sesquiterpenoid compound characterized by the presence of a 2-methylhept-2-en-4-one structure, with a 4-methylphenyl group substitution at position 6. It has been isolated from the plant Peltophorum dasyrachis and holds potential applications in various industries due to its unique chemical properties.
Uses
Used in Pharmaceutical Industry:
ar-Turmerone is used as a bioactive compound for its potential therapeutic effects. ar-Turmerone has demonstrated anti-inflammatory, antioxidant, and neuroprotective properties, making it a promising candidate for the development of new drugs targeting various health conditions.
Used in Cosmetic Industry:
In the cosmetic industry, ar-Turmerone is used as an ingredient for its anti-inflammatory and antioxidant properties. It can be incorporated into skincare products to help reduce inflammation, protect the skin from oxidative stress, and promote overall skin health.
Used in Flavor and Fragrance Industry:
Due to its unique aroma and flavor profile, ar-Turmerone is used as a component in the flavor and fragrance industry. It can be utilized to create natural and complex scents for perfumes, as well as to enhance the taste and aroma of various food products.
Used in Agricultural Industry:
ar-Turmerone's bioactive properties also make it a potential candidate for use in the agricultural industry. It could be employed as a natural pesticide or fungicide, helping to protect crops from pests and diseases while minimizing the environmental impact of synthetic chemicals.
Synthesis Reference(s)
The Journal of Organic Chemistry, 38, p. 2909, 1973 DOI: 10.1021/jo00956a039Synthetic Communications, 11, p. 579, 1981 DOI: 10.1080/00397918108063627Tetrahedron Letters, 20, p. 1519, 1979 DOI: 10.1016/S0040-4039(01)86195-5
Check Digit Verification of cas no
The CAS Registry Mumber 532-65-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,3 and 2 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 532-65:
(5*5)+(4*3)+(3*2)+(2*6)+(1*5)=60
60 % 10 = 0
So 532-65-0 is a valid CAS Registry Number.
InChI:InChI=1/C15H22O/c1-11(2)9-15(16)10-13(4)14-7-5-12(3)6-8-14/h5-7,9,13-14H,8,10H2,1-4H3
532-65-0Relevant articles and documents
Access to Chiral HWE Reagents by Rhodium-Catalyzed Asymmetric Arylation of γ,δ-Unsaturated β-Ketophosphonates
Yin, Long,Zhang, Dewei,Xing, Junhao,Wang, Yuhan,Wu, Changhui,Lu, Tao,Chen, Yadong,Hayashi, Tamio,Dou, Xiaowei
, p. 5869 - 5875 (2018)
Asymmetric arylation of ?,?-unsaturated β-ketophosphonates with arylboronic acids is reported. By using the (R)-diene? ligated rhodium(I) chloride complex as a catalyst under none basic conditions, the corresponding β-ketophosphonates bearing a ?-chiral center were obtained in high yields (up to 99%) with good to excellent enantioselectivities (up to >99% ee). The enantioenriched products can be readily converted to diverse chiral β′-aryl enones by the Horner-Wadsworth-Emmons reaction.
Cobalt-Catalyzed Enantioselective Synthesis of Chiral gem-Bis(boryl)alkanes
Teo, Wei Jie,Ge, Shaozhong
supporting information, p. 12935 - 12939 (2018/09/20)
We report an asymmetric synthesis of enantioenriched gem-bis(boryl)alkanes in an enantioselective diborylation of 1,1-disubstituted alkenes catalyzed by Co(acac)2/(R)-DM-segphos. A range of activated and unactivated alkenes underwent this asymmetric diborylation in the presence of cyclooctene as a hydrogen acceptor, affording the corresponding gem-bis(boryl)alkanes with high enantioselectivity. The synthetic utility of these chiral organoboronate compounds was demonstrated through several stereospecific derivatizations and the synthesis of sesquiterpene and sesquiterpenoid natural products.
Highly efficient Rh-catalyzed asymmetric hydrogenation of α,β-unsaturated nitriles
Yan, Qiaozhi,Kong, Duanyang,Li, Meina,Hou, Guohua,Zi, Guofu
, p. 10177 - 10181 (2015/09/01)
A highly efficient enantioselective hydrogenation of α,β-unsaturated nitriles catalyzed by Rh-(R,R)-f-spiroPhos complex has been developed. With Rh-(R,R)-f-spiroPhos catalyst and under mild conditions, a wide range of α,β-unsaturated nitriles including the (E)- and (Z)-isomers of 3-alkyl-3-aryl, 3,3-diaryl, and 3,3-dialkyl α,β-unsaturated nitriles were hydrogenated to the corresponding chiral nitriles with excellent enantioselectivities (up to 99.9% ee) and high turnover numbers (TON up to 10,000).
