53271-52-6

Basic information

• Product Name: Ethanedione, bis[2-(methylthio)phenyl]-
• CAS NO: 53271-52-6
• Molecular Formula: C16H14O2S2
• Molecular Weight: 302.418
• Mol File: 53271-52-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanedione, bis[2-(methylthio)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanedione, bis[2-(methylthio)phenyl]-(53271-52-6)
• EPA Substance Registry System: Ethanedione, bis[2-(methylthio)phenyl]-(53271-52-6)

Safety Data

• Hazardous Substances Data: 53271-52-6(Hazardous Substances Data)

Upstream product

• 77418-23-6 2-(Methylthio)thiobenzoesaeure-S-mesitylester 
• 77408-42-5 2-Methylthiobenzoesaeuremesitylester 
• 7022-45-9 2-(methylsulfanyl)benzaldehyde 
• 77408-46-9 2.2'-Bis(methylthio)benzoin 
• 1442-03-1 2-methylsulfanyl-benzoyl chloride 
• 77408-41-4 2-(Methylsulfinyl)thiobenzoesaeure-S-mesitylester 

Relevant articles and documents

Synthesis of S-Substituted Benzils and Some Hindered Biphenyls

Three methylthio and/or methylsulfinyl substituted benzils (2, 6 and 7) have been synthesized on photo- or thermochemical routes, respectively.Photodecarboxylation of some new different substituted mesityl benzoates (1a-e) leads to hindered biphenyls (3a-e) accompanied sometimes by aldehyde (4a-c) and benzil formation (2) due to compatitive α-cleavage and subsequent stabilization processes of such generated free aroyl radicals.A short summary on constitutional conditions for intramolecular photoredox reactions of ortho functionalized aryl sulfinyl compounds is presented. - Keywords: Photodecarboxylations, α-Cleavages, Photoredox Reactions, Sulfoxides