77408-41-4

Basic information

• Product Name: Benzenecarbothioic acid, 2-(methylsulfinyl)-, S-(2,4,6-trimethylphenyl) ester
• CAS NO: 77408-41-4
• Molecular Formula: C17H18O2S2
• Molecular Weight: 318.461
• Mol File: 77408-41-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, 2-(methylsulfinyl)-, S-(2,4,6-trimethylphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, 2-(methylsulfinyl)-, S-(2,4,6-trimethylphenyl) ester(77408-41-4)
• EPA Substance Registry System: Benzenecarbothioic acid, 2-(methylsulfinyl)-, S-(2,4,6-trimethylphenyl) ester(77408-41-4)

Safety Data

• Hazardous Substances Data: 77408-41-4(Hazardous Substances Data)

Upstream product

• 1442-03-1 2-methylsulfanyl-benzoyl chloride 
• 6127-91-9 sodium 2,4,6-trimethylbenzenethiolate 
• 77418-23-6 2-(Methylthio)thiobenzoesaeure-S-mesitylester 

Downstream Products

• 1483-92-7 bis(2,4,6-trimethylphenyl)disulfide 
• 77418-23-6 2-(Methylthio)thiobenzoesaeure-S-mesitylester 
• 3724-10-5 2-(methylthio)benzoic acid 
• 53271-52-6 2.2'-Bis(methylthio)benzil 
• 7022-45-9 2-(methylsulfanyl)benzaldehyde 
• 77408-46-9 2.2'-Bis(methylthio)benzoin 

Relevant articles and documents

Synthesis of S-Substituted Benzils and Some Hindered Biphenyls

Three methylthio and/or methylsulfinyl substituted benzils (2, 6 and 7) have been synthesized on photo- or thermochemical routes, respectively.Photodecarboxylation of some new different substituted mesityl benzoates (1a-e) leads to hindered biphenyls (3a-e) accompanied sometimes by aldehyde (4a-c) and benzil formation (2) due to compatitive α-cleavage and subsequent stabilization processes of such generated free aroyl radicals.A short summary on constitutional conditions for intramolecular photoredox reactions of ortho functionalized aryl sulfinyl compounds is presented. - Keywords: Photodecarboxylations, α-Cleavages, Photoredox Reactions, Sulfoxides