533928-74-4Relevant articles and documents
Synthesis, crystal structure, electrochemical property, and antioxidant activity of copper(II) complex based on 4-butyloxy-2,6-bis(1-methyl-2-benzimidazolyl)pyridine
Pan, Rong-kai,Li, Guo-bi,Liu, Sheng-gui,Zhou, Xiao-ping,Yang, Gui-zhen
, p. 1189 - 1196 (2016)
Abstract: A new copper(II) complex [Cu(bmbp)Cl2]·DMF, where bmbp is 4-butyloxy-2,6-bis(1-methyl-2-benzimidazolyl)pyridine, was synthesized and characterized by X-ray single-crystal structure analysis. The complex crystallizes in triclinic, space group P-1 with a?=?8.4551(3)??, b?=?12.8262(4)??, c?=?14.7111(5)??, α?=?64.335(3)°, β?=?75.314(3)°, γ?=?86.749(2)°, V?=?1388.42(8)??3, Z?=?2. The Cu(II) ion adopts a distorted trigonal bipyramidal geometry coordinated by three nitrogen atoms of the ligand and two chloride atoms. TG analysis showed that the complex has high thermal stability. Electrochemical measuring exhibited an irreversible one-electron transfer process. DPPH radical scavenging assay showed that the ligand and its Cu(II) complex exhibited much lower antioxidant activity than that of ascorbic acid. Graphical abstract: [Figure not available: see fulltext.]
"Janus-type" ruthenium complex bearing both phosphonic acids and pyrene groups for functionalization of ITO and HOPG surfaces
Yang, Li,Ozawa, Hiroaki,Koumoto, Mayuko,Yoshikawa, Kai,Matsunaga, Mariko,Haga, Masa-Aki
supporting information, p. 160 - 162 (2015/02/19)
A novel Janus-type ruthenium complex bearing both phosphonic acid and pyrene groups was tethered to both ITO and HOPG surfaces in different tethering modes. On the ITO surface, the phosphonic groups were selectively attached to the ITO, resulting in the h
Conjugated polymer with benzimidazolylpyridine ligands in the side chain: Metal ion coordination and coordinative self-assembly into fluorescent ultrathin films
Welterlich, Irina,Tieke, Bernd
scheme or table, p. 4194 - 4203 (2012/05/04)
The synthesis and characteristic properties of a new conjugated copolymer with poly(phenylene-alt-fluorene) main chain and 2,6-bis(1′- methylbenzimidazolyl)pyridine (bip) ligands attached to the main chain via flexible spacer groups are described. The cop