53742-62-4

Basic information

• Product Name: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-
• CAS NO: 53742-62-4
• Molecular Formula: C12H21NSi
• Molecular Weight: 207.391
• Mol File: 53742-62-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-(53742-62-4)
• EPA Substance Registry System: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-(53742-62-4)

Safety Data

• Hazardous Substances Data: 53742-62-4(Hazardous Substances Data)

Upstream product

• 29681-57-0 tert-butyldimethylsilane 
• 62-53-3 aniline 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 1227476-15-4 Azobenzene 
• 542-69-8 1-iodo-butane 
• 109-65-9 1-bromo-butane 

Downstream Products

• 62-53-3 aniline 
• 93066-14-9 C₁₂H₂₀NSi 
• 2739-12-0 N-methylaniline hydrochloride 
• 86518-04-9 1-tert-butyl-N,1,1-trimethyl-N-phenylsilanamine 
• 93066-32-1 C₁₆H₃₀NO₂PSi 

Relevant articles and documents

Highly efficient chemoselective N-TBS protection of anilines under exceptional mild conditions in the eco-friendly solvent 2-methyltetrahydrofuran

A straightforward chemoselective protection of anilines as N-TBS derivatives is described by using a suitable deprotonation of the amine with methyllithium in the environmentally friendly and safer substitute of THF, 2-methyltetrahydrofuran, under exceptional mild reaction conditions (0 °C, 30 min). Interestingly, the protecting group maybe cleaved efficiently by simple treatment of N-TBS-anilines with silica gel in ethanol-water.

Novel Syntheses of Bis(trialkylsilyl)amines by Reductive Trialkylsilylation of Azo Compounds

Reduction of azo compounds with a system of a trialkylchlorosilane and lithium has been found to afford bis(trialkylsilyl)amines in the presence of a transition metal halide as a catalyst in THF.The reaction course was significantly modified by using t-butyldimethylchlorosilane as a trialkylchlorosilane.

SELECTIVE N-MONOMETHYLATION OF PRIMARY AMINES via N-TRIALKYLSILYL-LITHIOAMINES

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