5393-55-5Relevant articles and documents
Synthesis and crystal structure of 2-aminoacetyl-1,3,4-thiadiazole
Kadirova,Nuralieva,Alieva,Talipov,Tilyakov,Parpiev
, p. 1962 - 1964 (2005)
2-Aminoacetyl-1,3,4-thiadiazole was synthesized, and its structure was studied. In crystal, the thiadiazole molecules form hydrogen-bonded endless one-dimensional chains related by the glide reflection plane.
1H, 13C, 15N and19F NMR study of acetylation products of heterocyclic thiosemicarbazones
Larina, Lyudmila I.,Elokhina, Valentina N.,Yaroshenko, Tatyana I.,Nakhmanovich, Anatolii S.,Dolgushin, Gennadii V.
, p. 667 - 673 (2008/03/14)
Novel 2-acetylamino-4-acetyl-5-aryl(heteryl)-1,3,4-thiadiazolines, 2-acetylamino-5-aryl(heteryl)-1,3,4-thiadiazoles, and some of their salts were prepared and studied by multinuclear 1H, 13C, 15N, 19F and 2D NMR
Synthesis, oxidation and dehydrogenation of cyclic N,O- and N,S-acetals. Part 1. Transformation of N,S-acetals: 3-acyl-1,3,4-thiadiazolines
Somogyi, Laszlo
, p. 2243 - 2267 (2007/10/03)
Aldehyde and ketone thiosemicarbazones are synthesized and cyclized into 3-acyl-1,3,4-thiadiazolines under acylating conditions. Reactions of the 2-monosubstituted heterocycles with oxidizing and dehydrogenating agents (KMnO4 or for the first time with CAN, DDQ, IBDA) lead to the formation of thiadiazoles. CAN oxidation of 2,2-disubstituted 3-acyl-1,3,4-thiadiazolines regenerates the parent ketones efficiently.