548780-42-3

Basic information

• Product Name: t-butyl triphenylsilyl(phenylmethyl)carbamate
• Synonyms: t-butyl triphenylsilyl(phenylmethyl)carbamate
• CAS NO: 548780-42-3
• Molecular Weight: 465.667
• Mol File: 548780-42-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: t-butyl triphenylsilyl(phenylmethyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl triphenylsilyl(phenylmethyl)carbamate(548780-42-3)
• EPA Substance Registry System: t-butyl triphenylsilyl(phenylmethyl)carbamate(548780-42-3)

Safety Data

• Hazardous Substances Data: 548780-42-3(Hazardous Substances Data)

Upstream product

• 42116-44-9 N-tert-butoxycarbonylbenzylamine 
• 18752-21-1 allyltriphenylsilane 

Downstream Products

• 548780-40-1 tert-butyl [(triphenylsilanyl)phenylmethyl]carbamate 

Relevant articles and documents

Asymmetric synthesis of α-amino allyl, benzyl, and propargyl silanes by metalation and rearrangement

(Matrix presented) Metalation of a Boc-protected N-silylamine α to nitrogen results in migration of the silicon from nitrogen to carbon (reverse aza-Brook rearrangement), yielding an α-amino silane. The Boc group acts initially as a metalation-directing g