54879-92-4Relevant articles and documents
Step and redox efficient nitroarene to indole synthesis
?zkaya, Bünyamin,Bub, Christina L.,Patureau, Frederic W.
supporting information, p. 13185 - 13188 (2020/11/09)
Step and redox efficiencies are a rising priority in synthetic method development, in order to make synthetic processes more sustainable and more affordable. Herein, a step and redox efficient nitroarene to indole synthesis is developed, in sharp contrast to the rich literature on the construction of indoles. Elemental zinc was found to be the best terminal reductant. This journal is
A palladium/carbon as catalyst preparation of indole compounds method (by machine translation)
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Paragraph 0029; 0030; 0031; 0033, (2018/06/15)
The present invention provides a palladium/carbon as catalyst preparation of indole compounds method, aniline and its analogs in the palladium/carbon with the alkyne under the action of the catalytic cyclization reaction, to form the corresponding indoles. This method has the advantages of: simple preparation method, the raw material is cheap, high yield, without protection of inert gas, the reaction temperature is relatively mild. (by machine translation)
Transition-metal-free, visible-light-mediated cyclization of: O -azidoarylalkynes with aryl diazonium salts
Jin, Cheng,Su, Lianzheng,Ma, Daxi,Cheng, Mingrong
supporting information, p. 14053 - 14056 (2017/11/28)
Visible light along with 3 mol% eosin Y catalyzes the cyclization reaction of o-azidoarylalkynes with aryl diazonium salts by a photoredox process. We have investigated the scope of the reaction for several aryl diazonium salts and o-azidoarylalkynes. The general and easy procedure provides a transition-metal-free alternative for the formation of unsymmetrical 2,3-diaryl-substitued indoles.