56475-33-3

Basic information

• Product Name: 1-Propanone, 3-methoxy-1-(4-methoxyphenyl)-
• CAS NO: 56475-33-3
• Molecular Formula: C11H14O3
• Molecular Weight: 194.23
• Mol File: 56475-33-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 3-methoxy-1-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 3-methoxy-1-(4-methoxyphenyl)-(56475-33-3)
• EPA Substance Registry System: 1-Propanone, 3-methoxy-1-(4-methoxyphenyl)-(56475-33-3)

Safety Data

• Hazardous Substances Data: 56475-33-3(Hazardous Substances Data)

Upstream product

• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 67-56-1 methanol 
• 7448-86-4 1-(4-methoxyphenyl)prop-2-en-1-one 
• 173019-85-7 3-bromo-1-(4-methoxyphenyl)propyne 
• 1416983-93-1 1-(3-hydroperoxyprop-1-ynyl)-4-methoxybenzene 
• 37614-59-8 4-(4-methoxyphenyl)prop-2-yn-1-ol 
• 35999-20-3 3-chloro-4'-methoxypropiophenone 
• 696-62-8 para-iodoanisole 

Downstream Products

• 57012-40-5 2-Methyl-2-<3-(p-methoxyphenyl)-5-methoxy-pent-2-enyl>-cyclopentan-1,3-dion 
• 56475-36-6 2-[5-Methoxy-3-(4-methoxy-phenyl)-pentyl]-2-methyl-cyclopentane-1,3-dione 
• 57012-41-6 2-Methyl-2-<3-(p-methoxyphenyl)-5-methoxy-pent-2-enyl>-cyclopentan-1,3-dion 

Relevant articles and documents

Bi(OTf)3-catalyzed tandem Meyer-Schuster rearrangement and 1,4-addition to the resulting vinyl ketone

Bi(OTf)3-catalyzed Meyer-Schuster rearrangement of electron-rich propargyl alcohols, followed by 1,4-addition of the resulting vinyl ketone, proceeded smoothly though Meyer-Schuster rearrangement of primary propargyl alcohols is rare. This tandem reaction can be extended to an intramolecular version, featuring a one-pot dihydroquinolone synthesis. (Chemical Equation Presented).

Unveiling the reactivity of propargylic hydroperoxides under gold catalysis

Controlled gold-catalyzed reactions of primary and secondary propargylic hydroperoxides with a variety of nucleophiles including alcohols, phenols, 2-hydroxynaphthalene-1,4-dione, and indoles allow the direct and efficient synthesis of β-functionalized ke

Highly efficient p-toluenesulfonic acid-catalyzed alcohol addition or hydration of unsymmetrical arylalkynes

Under a catalytic amount of PTSA in aqueous or alcoholic media, activated unsymmetrical arylalkynes 1 undergo regioselective water or alcohol addition to afford successfully carbonyl compounds 2 in good to excellent yields. This new environmentally metal-free procedure, which afforded only Markovnikov adducts, is characterized by the mildness of acidic conditions and the excellent regio- and chemoselectivity.