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56475-88-8

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56475-88-8 Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 103, p. 1172, 1981 DOI: 10.1021/ja00395a029Organic Syntheses, Coll. Vol. 7, p. 307, 1990

Check Digit Verification of cas no

The CAS Registry Mumber 56475-88-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,6,4,7 and 5 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 56475-88:
(7*5)+(6*6)+(5*4)+(4*7)+(3*5)+(2*8)+(1*8)=158
158 % 10 = 8
So 56475-88-8 is a valid CAS Registry Number.
InChI:InChI=1/C7H13NO3/c1-10-6-4-3-5-8(6)7(9)11-2/h6H,3-5H2,1-2H3

56475-88-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl 2-methoxypyrrolidine-1-carboxylate

1.2 Other means of identification

Product number -
Other names 2-Methoxy-pyrrolidine-1-carboxylic acid methyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:56475-88-8 SDS

56475-88-8Relevant articles and documents

Catalytic Asymmetric Additions of Enol Silanes to In Situ Generated Cyclic, Aliphatic N-Acyliminium Ions

Aukland, Miles H.,Grossmann, Oleg,Lee, Sunggi,List, Benjamin,Maji, Rajat

supporting information, (2022/01/19)

Strong and confined imidodiphosphorimidate (IDPi) catalysts enable highly enantioselective substitutions of cyclic, aliphatic hemiaminal ethers with enol silanes. 2-Substituted pyrrolidines, piperidines, and azepanes are obtained with high enantioselectiv

One-pot conversion of proline derivatives into iodinated iminosugar-based nucleosides, useful precursors of highly functionalized nucleoside analogues

Boto, Alicia,Hernandez, Dacil,Hernandez, Rosendo

scheme or table, p. 6633 - 6642 (2011/02/25)

Readily available proline derivatives can be transformed in one step into β-iodinated iminosugar-based nucleosides, under very mild conditions. The method couples a tandem radical decarboxylation-oxidation-β-iodination to the addition of nitrogen bases. T

Photochemical rearrangement of N -chlorolactams: A route to N -heterocycles through concerted ring contraction

Winter, Dana K.,Drouin, Alexandre,Lessard, Jean,Spino, Claude

supporting information; experimental part, p. 2610 - 2618 (2010/06/17)

We report a novel ring contraction allowing the direct conversion of N-chlorolactams to their corresponding ring-contraction N-heterocycles upon photolysis. Results show that the rearrangement occurs with a variety of N-chlorolactams and that the greater the substitution at the migrating carbon, the greater the yield of product. Importantly, stereochemistry at the migrating carbon is conserved in the product. Rearranged products were isolated as their methyl carbamates in yields varying from 17% to 58%, with the major side product being the recyclable parent lactam.

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