56587-85-0

Basic information

• Product Name: Ethanone, 1-(4-chlorophenyl)-, [1-(4-chlorophenyl)ethylidene]hydrazone, (E,E)-
• CAS NO: 56587-85-0
• Molecular Formula: C16H14Cl2N2
• Molecular Weight: 305.207
• Mol File: 56587-85-0.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(4-chlorophenyl)-, [1-(4-chlorophenyl)ethylidene]hydrazone, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(4-chlorophenyl)-, [1-(4-chlorophenyl)ethylidene]hydrazone, (E,E)-(56587-85-0)
• EPA Substance Registry System: Ethanone, 1-(4-chlorophenyl)-, [1-(4-chlorophenyl)ethylidene]hydrazone, (E,E)-(56587-85-0)

Safety Data

• Hazardous Substances Data: 56587-85-0(Hazardous Substances Data)

Upstream product

• 61185-76-0 1-(p-chlorophenyl)-1-diazoethane 
• 354-48-3 1,1,1-tribromotrifluoroethane 
• 40137-41-5 (1-(4-chlorophenyl)ethylidene)hydrazine 
• 75230-50-1 p-chloroacetophenone tosylhydrazone 
• 1956-39-4 4-chloroacetophenone oxime 
• 3252-43-5 dibromoacetonitrile 
• 56-23-5 tetrachloromethane 
• 99-91-2 para-chloroacetophenone 
• 79881-23-5 t-butyl β-methyl-β-(p-chlorophenyl)glycidate 

Downstream Products

• 1198575-42-6 1-methyl-3,4-diphenyl-6-chloro-isoquinoline 
• 1257525-32-8 (E)-3-(4-chlorophenyl)-3-[3-(4-chlorophenyl)-1H-1-pyrazolyl]-2-propenal 
• 1313511-96-4 3-(4-chlorophenyl)-1-[1-(4-chlorophenyl)vinyl]-1H-4-pyrazolecarbaldehyde 
• 1189947-91-8 (4-chlorophenyl)(methyl)(3,5-xylyl)methane 
• 1189947-92-9 C₂₀H₁₇Cl 
• 90861-57-7 [(E)-3-(4-Chloro-phenyl)-3-{N'-[1-(4-chloro-phenyl)-eth-(E)-ylidene]-hydrazino}-1-cyclohexyl-prop-2-en-(E)-ylidene]-carbamic acid ethyl ester 
• 90861-64-6 6-(4-Chloro-phenyl)-1-[1-(4-chloro-phenyl)-eth-(E)-ylideneamino]-4-cyclohexyl-1H-pyrimidin-2-one 
• 90861-72-6 1-Amino-6-(4-chloro-phenyl)-4-cyclohexyl-1H-pyrimidin-2-one 
• 99-91-2 para-chloroacetophenone 
• 64620-62-8 α-Brom-p-chloracetophenonazin 

Relevant articles and documents

Cp*Co(III)-catalyzed C[sbnd]H amidation of azines with dioxazolones

Cp*Co(III)-catalyzed direct C[sbnd]H amidation of azines has been developed. This conversion could proceed smoothly in the absence of external oxidants, acids or bases, with excellent regioselectivity and broad functional group tolerance. CO2 w

Cp*Co(iii)-catalyzed annulation of azines by C-H/N-N bond activation for the synthesis of isoquinolines

Herein, an efficient, atom economic and external oxidant free approach has been disclosed for the synthesis of isoquinolines. Azines were employed for annulation reactions with alkynes via sequential C-H/N-N bond activation using an air-stable cobalt catalyst. The method takes advantage of the incorporation of both the nitrogen atoms of azines into the desired isoquinoline products, offering the highest atom economy. In addition, the developed protocol works under external oxidant as well as silver salt free conditions. Furthermore, the established methodology features a relatively broad substrate scope with high product yields and scalability up to the gram level.

C[sbnd]N bond formation in alicyclic and heterocyclic compounds by amine-modified nanoclay

In the current protocol, amine functionalized montmorillonite K10 nanoclay (NH2-MMT) was applied to catalyze the formation of C[sbnd]N bonds in the synthesis of azines and 2-aminothiazoles at room temperature. In comparison with the current methods of C[sbnd]N bond formation, this approach displays specific advantages include atom economy, clean conversion, design for energy efficiency, the use of nontoxic and heterogeneous catalyst, higher purity and yields, safer solvent and reagents for this organic transformation.