5667-52-7

Basic information

• Product Name: 2,4-dimethoxy-1-(phenylsulfanyl)benzene
• Synonyms: 2,4-dimethoxy-1-(phenylsulfanyl)benzene
• CAS NO: 5667-52-7
• Molecular Weight: 246.33
• Mol File: 5667-52-7.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 2,4-dimethoxy-1-(phenylsulfanyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-dimethoxy-1-(phenylsulfanyl)benzene(5667-52-7)
• EPA Substance Registry System: 2,4-dimethoxy-1-(phenylsulfanyl)benzene(5667-52-7)

Safety Data

• Hazardous Substances Data: 5667-52-7(Hazardous Substances Data)

Upstream product

• 20469-63-0 1-iodo-2,4-dimethoxybenzene 
• 930-69-8 sodium thiophenolate 
• 98-09-9 benzenesulfonyl chloride 
• 151-10-0 1,3-Dimethoxybenzene 
• 873-55-2 sodium benzenesulfonate 
• 133730-34-4 2,4-dimethoxyphenylboronic acid 
• 5285-87-0 phenyl thiocyanate 
• 5296-64-0 allyl phenyl thioether 
• 108-98-5 thiophenol 
• 14204-24-1 N-(phenylthio)succinimide 
• 882-33-7 diphenyldisulfane 
• 4972-29-6 benzenesulphinyl chloride 
• 169216-70-0 4-Benzenesulfinyl-2,3,5,6-tetramethyl-phenol 
• 194720-38-2 2,3,5,6-tetramethyl-4-oxo-1-phenylthiocyclohexa-2,5-dienyl 2-chloroacetate 

Downstream Products

• 61945-91-3 4-benzenesulfonyl-resorcinol 
• 85576-36-9 6-benzenesulfonyl-7-hydroxy-4-methyl-coumarin 
• 15476-93-4 2,4-dimethoxy-1-(phenylsulfonyl)benzene 

Relevant articles and documents

Electrochemistry Enabled Nickel-Catalyzed Selective C?S Bond Coupling Reaction

This work describes an electrochemical enabled nickel-catalyzed chemoselective C?S bond coupling protocol for the production of aryl sulfides and sulfones. By simply switching the nickel catalysts and electrodes, this electrochemical C?S bond coupling has demonstrated excellent redox activity, scalability and sustainability. Furthermore, the mechanism for this electrochemical cross-coupling reaction has been investigated.

Transition-Metal-Free HFIP-Mediated Organo Chalcogenylation of Arenes/Indoles with Thio-/Selenocyanates

We have developed a protocol for the synthesis of diaryl thio-/selenoethers by the reaction of aryl chalcogenocyanates with electron rich arenes/hetero arenes via HFIP promoted C-H activation. The reaction produces chalcogenides in good to excellent yields under mild conditions without the need of a transition metal as a catalyst. The HFIP-mediated reactions tolerated a wide range of functional groups and set the stage for the synthesis of diversely decorated chalcogenides. A mechanism involving activation of the C-H bond through hydrogen bonding is proposed.