5676-62-0

Basic information

• Product Name: 2-[({[4,5-bis(4-chlorophenyl)-1H-1,2,4-triazol-4-ium-3-yl]sulfanyl}acetyl)carbonohydrazonoyl]-6-ethoxyphenolate
• CAS NO: 5676-62-0
• Molecular Formula: C₉H₇ClO₂
• Molecular Weight: 542.4369
• Mol File: 5676-62-0.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-[({[4,5-bis(4-chlorophenyl)-1H-1,2,4-triazol-4-ium-3-yl]sulfanyl}acetyl)carbonohydrazonoyl]-6-ethoxyphenolate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[({[4,5-bis(4-chlorophenyl)-1H-1,2,4-triazol-4-ium-3-yl]sulfanyl}acetyl)carbonohydrazonoyl]-6-ethoxyphenolate(5676-62-0)
• EPA Substance Registry System: 2-[({[4,5-bis(4-chlorophenyl)-1H-1,2,4-triazol-4-ium-3-yl]sulfanyl}acetyl)carbonohydrazonoyl]-6-ethoxyphenolate(5676-62-0)

Safety Data

• Hazardous Substances Data: 5676-62-0(Hazardous Substances Data)

Upstream product

• 1615-02-7 3-(4-chlorophenyl)prop-2-enoic acid 
• 201230-82-2 carbon monoxide 
• 66482-30-2 (Z)-1-bromo-2-(4-chlorophenyl)ethylene 
• 24653-99-4 (2RS,3SR)-2,3-dibromo-3-(4-chlorophenyl)propanoic acid 
• 31357-32-1 α,β-dibromo-p-chlorohydrocinnamic acid 
• 20754-24-9 methyl (Z)-3-(p-chlorophenyl)prop-2-enoate 
• 20026-96-4 ethyl 3-(4-chlorophenyl)propiolate 
• 63757-30-2 ethyl (Z)-3-(4-chlorophenyl)acrylate 
• 104-88-1 4-chlorobenzaldehyde 
• 873-73-4 4-n-chlorophenylacetylene 
• 3240-10-6 (4-chlorophenyl)propiolic acid 

Downstream Products

• 34576-85-7 3,6-Dichlor-benzo--thiophen-2-carbonsaeurechlorid 
• 59259-40-4 acide p-chloro phenyl-3 exo bicyclo<2.2.1> heptene-5 carboxylique-2 exo 
• 81509-21-9 (1S,3S,6S,7R,9R)-9-(4-Chloro-phenyl)-2-iodo-4-oxa-tricyclo[4.2.1.0^3,7]nonan-5-one 
• 18684-82-7 Z-1-chloro-4-(2-chloroethenyl)benzene 
• 59259-40-4 acide p-chloro phenyl-3 endo bicyclo<2.2.1>heptene-5 carboxylique-2 endo 
• 81509-29-7 p-Cl-phenyl-3 endo bicyclo<2.2.1>heptane carbolactone 2-6 
• 81509-26-4 p-chloro-phenyl-3 endo bicyclo<2.2.1> heptene-5 carboxylate endo-2 de methyle 

Relevant articles and documents

Semireduction of alkynoic acids via a transition metal-free α borylation-protodeborylation sequence

A method for the semi-reduction of alkynoic acids through an α-borylation and subsequent protodeborylation mechanism has been developed. The transition metal-free protocol is achieved through the activation of bis(pinacolato)diboron by an in situ generated carboxylate moiety yielding aryl acrylic acids. Our studies demonstrate an unprecedented dual role for the carboxylate anion that involves the activation of the diboron reagent and a directing effect in the α-borylation.

A linear solvation energy relationship study for the reactivity of 2-(4-substituted phenyl)-cyclohe-1-enecarboxylic, 2-(4-substituted phenyl)-benzoic, and 2-(4-substituted phenyl)-acrylic acids with diazodiphenylmethane in various solvents

The reactivities of 2-(4-substituted phenyl)-cyclohex-1-enecarboxylic acids, 2-(4-substituted phenyl)-benzoic acids, and 2-(4-substituted phenyl)-acrylic acids with diazodiphenylmethane in various solvents were investigated. To explain the kinetic results through solvent effects, the second-order rate constants of the examined acids were correlated using the Kamlet-Taft solvatochromic equation. The correlations of the kinetic data were carried out by means of multiple linear regression analysis, and the solvent effects on the reaction rates were analyzed in terms of initial and transition state contributions. The signs of the equation coefficients support the proposed reaction mechanism. The solvation models for all investigated carboxylic acids are suggested. The quantitative relationship between the molecular structure and the chemical reactivity is discussed, as well as the effect of geometry on the reactivity of the examined molecules.