5729-06-6

Basic information

• Product Name: N-BENZYL-2-NITROANILINE
• Synonyms: N-BENZYL-2-NITROANILINE;BENZYL-2-NITROANILINE;N-Benezyl-2-nitroaniline;BenzeneMethanaMine, N-(2-nitrophenyl)-;N-benzyl-2-nitrobenzenamine;2-nitro-N-(phenylmethyl)aniline;Benzylamine, n-(o-nitrophenyl)-
• CAS NO: 5729-06-6
• Molecular Formula: C₁₃H₁₂N₂O₂
• Molecular Weight: 228.25
• Mol File: 5729-06-6.mol
• Article Data: 70

Chemical Properties

• Boiling Point: 382.3°C at 760 mmHg
• Flash Point: 185°C
• Appearance: /
• Density: 1.258g/cm³
• Vapor Pressure: 4.75E-06mmHg at 25°C
• Refractive Index: 1.658
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• CAS DataBase Reference: N-BENZYL-2-NITROANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-BENZYL-2-NITROANILINE(5729-06-6)
• EPA Substance Registry System: N-BENZYL-2-NITROANILINE(5729-06-6)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 5729-06-6(Hazardous Substances Data)

Usage

General Description

N-Benzyl-2-nitroaniline is a chemical compound with the molecular formula C13H12N2O2. It is a pale yellow solid that is soluble in organic solvents and has a strong nitro-aromatic odor. N-BENZYL-2-NITROANILINE is commonly used as a chemical intermediate in the synthesis of various pharmaceuticals and dyes. It is also utilized in research and laboratory settings as a building block for the creation of other organic compounds. N-Benzyl-2-nitroaniline is considered to be harmful if ingested, inhaled, or absorbed through the skin, and proper safety precautions should be observed when handling and storing this chemical.

InChI:InChI=1/C13H12N2O2/c16-15(17)13-9-5-4-8-12(13)14-10-11-6-2-1-3-7-11/h1-9,14H,10H2

Upstream product

• 100-44-7 benzyl chloride 
• 88-74-4 2-nitro-aniline 
• 88-73-3 2-Chloronitrobenzene 
• 100-46-9 benzylamine 
• 577-19-5 2-nitrophenyl bromide 
• 528-29-0 1,2-Dinitrobenzene 
• 100-39-0 benzyl bromide 
• 7647-01-0 hydrogenchloride 
• 1493-27-2 ortho-nitrofluorobenzene 
• 501-53-1 benzyl chloroformate 
• 728-90-5 N-(2-nitrophenyl)benzanilide 
• 14717-15-8 N-(benzylidene)-2-nitroaniline 
• 100-52-7 benzaldehyde 
• 612-98-6 N-benzyl-N-phenylnitrous amide 

Downstream Products

• 5822-13-9 N-benzyl-1,2-phenylenediamine 
• 59277-10-0 benzoic acid-(N-benzyl-2-nitro-anilide) 
• 42909-13-7 acetic acid-(N-benzyl-2-nitro-anilide) 
• 20927-67-7 N-Benzyl-N-carbethoxyacetyl-o-nitro-anilin 
• 61154-54-9 [benzyl-(2-nitro-phenyl)-sulfamoyl]-acetic acid ethyl ester 
• 31493-51-3 1-benzyl-1,3-dihydro-2H-benzo-[d]-imidazole-2-thione 
• 100460-80-8 Benzyl-(2-nitro-phenyl)-carbamic acid ethyl ester 
• 760949-34-6 5-methylpyridine-2-carboxylic acid [benzyl(2-nitrophenyl)]amide 
• 4981-92-4 1-benzylbenzimidazole 
• 716-79-0 2-phenyl-1H-benzoimidazole 
• 28643-53-0 1,3-dihydro-1-(phenylmethyl)-2H-benzimidazol-2-one 
• 100460-84-2 (2-Amino-phenyl)-benzyl-carbamic acid ethyl ester 
• 4706-43-8 1-benzyl-1H-benzotriazole 
• 61154-85-6 2,2-dioxo-5-phenyl-1,2,3,5-tetrahydro-2λ⁶-benzo[c][1,2,5]thiadiazepin-4-one 

Relevant articles and documents

Influence of Symmetry on the Luminescence and Radiative Lifetime of Nine-Coordinate Europium Complexes

Homoleptic mononuclear nine-coordinate lanthanum(III) and europium(III) tris-complexes [Ln(N^N^O)3]·nH2O with two tridentate N-benzylbenzimidazole pyridine-2-carboxylates exhibit a rare C3-symmetry of the lanthanide coordi

Nucleophilic aromatic substitution reactions under aqueous, mild conditions using polymeric additive HPMC

The use of the inexpensive, benign, and sustainable polymer, hydroxypropyl methylcellulose (HPMC), in water enables nucleophilic aromatic subsitution (SNAr) reactions between various nucleophiles and electrophiles. The mild reaction conditions facilitate a broad functional group tolerance that can be utilized for subsequent derivatization for the synthesis of pharmaceutically relevant building blocks. The use of only equimolar amounts of all reagents and water as reaction solvent reveals the greenness and sustainability of the methodology presented herein.

Heterostructured Hybrid rGO@α-MnO2/rGO@δ-MnO2 Nanoflower: An Efficient Catalyst for Aerobic Solvent-Free N-Alkylation Reactions and Energy Storage Material

A new reduced graphene oxide (rGO) based bi-phasic crystal of MnO2, namely α-MnO2 nanorods and δ-MnO2 nanoflakes containing heterostructured hybrid nanoflower rGO@α-MnO2/rGO@δ-MnO2 has been fabricated through a facile hydrothermal method followed by annealing treatment. The successful synthesis of the hybrid material was studied by XRD, Raman, BET, FESEM with EDX, FTIR and TEM analyses. An efficient N-alkylation reaction of substituted aromatic amines with aromatic alcohols was carried out under solvent-free aerobic conditions in the presence of catalytic amount of rGO@α-MnO2/rGO@δ-MnO2. The catalyst shows excellent activity in terms of high yields (up to 98 %), short reaction time (10 h) along with a simple work-up process. The spent material can be regenerated several times without causing any serious decrease in catalytic activity. Moreover, cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and cyclic stability techniques were executed to evaluate the performances of rGO@α-MnO2, rGO@δ-MnO2, and rGO@α-MnO2/rGO@δ-MnO2 as energy storage materials. Among all those materials, rGO@α-MnO2/rGO@δ-MnO2 exhibited a proficient specific capacitance, CS (267 F/g at 1 A/g) along with excellent cycling ability (～83 % retention up to 10000 cycles). The superb electrochemical performance of rGO@α-MnO2/rGO@δ-MnO2 might be ascribed to the combination of bi-phasic α-MnO2 and δ-MnO2 with rGO sheets, resulting in a flower-like structure.