57684-11-4

Basic information

• Product Name: Podocarpa-9(11)-ene-12-one
• Synonyms: (4bS)-1,4b,5,6,7,8,8aβ,9,10,10aα-Decahydro-4bα,8,8-trimethylphenanthren-3(2H)-one;Podocarpa-9(11)-ene-12-one
• CAS NO: 57684-11-4
• Molecular Formula: C₁₇H₂₆O
• Molecular Weight: 246.39
• Mol File: 57684-11-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 352.5±9.0 °C(Predicted)
• Appearance: /
• Density: 1.00±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Podocarpa-9(11)-ene-12-one(CAS DataBase Reference)
• NIST Chemistry Reference: Podocarpa-9(11)-ene-12-one(57684-11-4)
• EPA Substance Registry System: Podocarpa-9(11)-ene-12-one(57684-11-4)

Safety Data

• Hazardous Substances Data: 57684-11-4(Hazardous Substances Data)

Upstream product

• 5947-49-9 podocarpic acid 
• 10064-08-1 (+)-(5S,10S)-12-methoxypodocarpa-8,11,13-triene 

Downstream Products

• 85706-63-4 C₂₇H₄₀O₃S 

Relevant articles and documents

The formation of 8-epipodocarp-9(11)en-12-one in the course of the preparation of podocarp-9(11)-en-12-one from O-methylpodocarpane and related studies

The preparation of podocarp-9(11)-en-12-one (1a) from O-methylpodocarpane (2) was investigated with the aim of clarifying whether 8-epipodocarp-9(11)-en-12-one (1b) is formed to any extent during the early stages of the process. This study, supported by molecular-mechanics calculations, resulted in the preparation, along with 1a, of the previously undescribed 1b, which could be fully characterized by means of 2D-NMR experiments. Significant differences recorded in the NMR and NOESY spectra of 1a and 1b were of diagnostic value in establishing the relative configuration at C(8) and possibly might be helpful to solve similar problems on podocarp-9(11)-en-12-one derivatives.