10064-08-1

Basic information

• Product Name: (+)-(5S,10S)-12-methoxypodocarpa-8,11,13-triene
• Synonyms: (+)-(5S,10S)-12-methoxypodocarpa-8,11,13-triene
• CAS NO: 10064-08-1
• Molecular Weight: 258.404
• Mol File: 10064-08-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (+)-(5S,10S)-12-methoxypodocarpa-8,11,13-triene(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(5S,10S)-12-methoxypodocarpa-8,11,13-triene(10064-08-1)
• EPA Substance Registry System: (+)-(5S,10S)-12-methoxypodocarpa-8,11,13-triene(10064-08-1)

Safety Data

• Hazardous Substances Data: 10064-08-1(Hazardous Substances Data)

Upstream product

• 38011-83-5 trans-1-(4,8-dimethylnona-3,7-dien-1-yl)-4-methoxybenzene 
• 4698-08-2 (E)-geranic acid 
• 81026-41-7 3-(p-methoxyphenylethyl)-2,4,4-trimethylcyclohexanol 
• 80994-23-6 trans-1-(p-methoxyphenylethyl)-2,2,6-trimethylcyclohexanol 
• 198631-12-8 2-[2-(2-Bromo-4-methoxyphenyl)ethyl]-3,3-dimethyl-1-methylenecyclohexane 
• 80994-24-7 1-(p-methoxyphenylethyl)-2,6,6-trimethylcyclohex-1-ene 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 

Downstream Products

• 10064-08-1 1,2,3,4,4a,9,10,10a-Octahydro-6-methoxy-1,1,4a-trimethylphenanthrene 
• 80994-24-7 1-(p-methoxyphenylethyl)-2,6,6-trimethylcyclohex-1-ene 
• 80994-32-7 6-methoxy-1,4a,10a-trimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene 
• 511-05-7 (+)-sugiol 
• 511-05-7 sugiol 
• 66890-62-8 12-benzyloxypodocarpa-8,11,13-triene 
• 113332-25-5 (+/-)-nimbidiol 
• 84104-87-0 (4aS,10aS)-1,2,3,4,4a,9,10,10a-octahydro-6,7-dihydroxy-8-isopropyl-1,1,1,4a-trimethylphenanthrene 
• 51847-85-9 13-methoxytotara-8,11,13-trien-12-ol 
• 68042-46-6 premnolal 
• 113332-25-5 nimbidiol 
• 514-62-5 ferruginol 
• 57684-11-4 (-)-podocarp-9⁽¹¹⁾-en-12-one 
• 3772-54-1 (+/-)-nimbiol methyl ether 

Relevant articles and documents

Ru(III)-Catalyzed Cyclization of Arene-Alkene Substrates via Intramolecular Electrophilic Hydroarylation

(Matrix presented) We herein report that RuCl3/AgOTf has proven to be a hydroarylation catalyst with an efficiency and scope superior to previously known methods. This catalyst demonstrated consistent performance with arene-ene substrates of diverse structural features, providing good to excellent yields of cyclization products (chromanes, tetralins, terpenoids, dihydrocoumarins).

Synthesis of (+)- and (-)-ferruginol via asymmetric cyclization of a polyene

Stereoselectivity of modified polyenes which have a terminal benzene ring was found to be dependent on the size of substituent on the adjacent asymmetric carbon to the terminal benzene ring of the polyenes. (R)-(+)-2′-Hydroxy-1,1′-binaphthyl-2-yl(2R)-2-(4-methoxyphenyl)-5,9- dimethyldeca-4,8-dienoate gave(R)-(+)-2′-hydroxy-1,1′-binaphthyl-2-yl (4aS,9 R, 10aS)-1,2,3,4,4a,9,10,10a-octahydro-6-methoxy-1,1,4a-trimethylphenanthene-9- carboxylate stereoselectively by treatment with BF3-Et2O in nitromethane. The products were elaborated to (+)-ferruginol 1. (-)-Ferruginol 2 and (±)-ferruginol 3 were also synthesized via a similar synthetic route. The Royal Society of Chemistry 2000.

Stereoselective synthesis of (-)-6,7-dehydroferruginyl methyl ether

A stereoselective synthetic route to (-)-6,7-dehydroferruginyl methyl ether was developed from (S)-(-)-α-cyclocitral. Copyright (C) 2000 Elsevier Science Ltd.