58435-70-4

Basic information

• Product Name: cyclohexyl methoxymethyl ketone
• Synonyms: cyclohexyl methoxymethyl ketone
• CAS NO: 58435-70-4
• Molecular Weight: 156.225
• Mol File: 58435-70-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cyclohexyl methoxymethyl ketone(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl methoxymethyl ketone(58435-70-4)
• EPA Substance Registry System: cyclohexyl methoxymethyl ketone(58435-70-4)

Safety Data

• Hazardous Substances Data: 58435-70-4(Hazardous Substances Data)

Upstream product

• 1738-36-9 2-methoxyacetonitrile 
• 931-51-1 cyclohexylmagnesiumchloride 
• 14704-14-4 (methoxymethyl)trimethylsilane 
• 108-94-1 cyclohexanone 
• 80783-98-8 N-methoxy-N-methylcyclohexanecarboxamide 
• 107-30-2 chloromethyl methyl ether 

Relevant articles and documents

Highly efficient synthesis of functionalized α-oxyketones: Via Weinreb amides homologation with α-oxygenated organolithiums

An efficient, chemoselective homologation of Weinreb amides to the corresponding variously substituted α-oxyketones has been developed via the addition of lithiated α-oxygenated species. This one-step, experimentally easy, high yielding protocol is amenable not only for accessing simple α-oxyketones but also for more complex substituted ones ranging from primary and secondary alkyl-type to aromatic ones. Full delivery of the stereochemical information contained in the starting materials is observed through both the employment of enantioenriched Weinreb amides and optically active organolithium species.