58706-96-0

Basic information

• Product Name: methyl cis-2-(2-oxopropyl)cyclohexane-1-carboxylate
• CAS NO: 58706-96-0
• Molecular Weight: 198.262
• Mol File: 58706-96-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl cis-2-(2-oxopropyl)cyclohexane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl cis-2-(2-oxopropyl)cyclohexane-1-carboxylate(58706-96-0)
• EPA Substance Registry System: methyl cis-2-(2-oxopropyl)cyclohexane-1-carboxylate(58706-96-0)

Safety Data

• Hazardous Substances Data: 58706-96-0(Hazardous Substances Data)

Upstream product

• 2695-47-8 6-Bromo-1-hexene 
• 128488-55-1 3-methyl-7-oxo-4,6-dioxatricyclo<6.3.0.0^3.8>dodecane-5-spirocyclohexane 
• 128488-49-3 3-(5-hexenyl)-2-methyl-4-oxo-1,5-dioxaspiro<5.5>undec-2-ene 
• 128488-46-0 t-butyl 2-acetyl-5-octenoate 
• 125258-89-1 (+/-)-(1RS,2RS)-2-(methoxycarbonyl)cyclohexane acetic acid 
• 14736-49-3 2-(2-(methoxycarbonyl)phenyl)acetic acid 
• 186581-53-3 diazomethane 
• 125259-02-1 (1S,2S)-2-Chlorocarbonylmethyl-cyclohexanecarboxylic acid methyl ester 
• 70302-37-3 2-acetonyl-cyclohexanecarboxylic acid 
• 18448-47-0 methyl cyclohex-1-ene-1-carboxylate 
• 13483-31-3 Acetone dimethylhydrazone 

Downstream Products

• 125258-98-2 (1S,2S)-2-((R)-2-Hydroxy-propyl)-cyclohexanecarboxylic acid hydrazide 

Relevant articles and documents

Use of 1,3-Dioxin-4-ones and Their Related Compounds in Synthesis. Part 28 . Asymmetric de Mayo Reactions Using Chiral Spirocyclic Dioxinones

The use of rigid spirocyclic dioxinones having 1-menthone as the chiral auxiliary as the enones in the photocycloaddition reactions opened novel methods for obtaining enantiomerically pure compounds, such as iridoids.Convex side preference of the sofa-conformation of these dioxinones in the photoaddition to cyclopentene increases up to 100percent by introducing either a bulky substituent or 5-hexenyl group at the 3-position to these dioxinones and, hence, highly asymmetric inter- and intramolecular de Mayo reactions have been disclosed.

Studies on Synthesis and Stereochemistry of 3-Methyloctahydroisocoumarins and 1-Methyloctahydro-3H-2-benzopyran-3-ones

Four stereoisomers of 3-methyloctahydroisocoumarins (4a-d) and two 1-methyloctahydro-3H-2-benzopyran-3-ones (10a,b) were synthesized.The stereochemical correlations including the configurations of the ring juncture and the methyl group and also the ring c