592510-51-5

Basic information

• Product Name: 1,3-Dioxolane, 2-[(1E)-2-(4-methoxyphenyl)ethenyl]-
• CAS NO: 592510-51-5
• Molecular Formula: C12H14O3
• Molecular Weight: 206.241
• Mol File: 592510-51-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolane, 2-[(1E)-2-(4-methoxyphenyl)ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane, 2-[(1E)-2-(4-methoxyphenyl)ethenyl]-(592510-51-5)
• EPA Substance Registry System: 1,3-Dioxolane, 2-[(1E)-2-(4-methoxyphenyl)ethenyl]-(592510-51-5)

Safety Data

• Hazardous Substances Data: 592510-51-5(Hazardous Substances Data)

Upstream product

• 123-08-0 4-hydroxy-benzaldehyde 
• 646-06-0 1,3-DIOXOLANE 
• 3179-10-0 (E)-1-methoxy-4-(2-nitrovinyl)benzene 
• 24680-50-0 4-methoxy-trans-cinnamaldehyde 
• 107-21-1 ethylene glycol 
• 52509-14-5 (1,3-dioxolan-2-yl-methyl)triphenylphosphonium bromide 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 37771-95-2 (E)-N-((E)-3-(4-methoxyphenyl)prop-2-en-1-ylidene)-1-(4-nitrophenyl)amine 
• 24680-50-0 4-methoxy-trans-cinnamaldehyde 

Relevant articles and documents

Improved one-pot synthesis of styryl tetrahydrofurans and cyclohexanes by radical addition to β-nitrostyrenes in the presence of benzoyl peroxide

Stereoselective styryl derivatives have been prepared based on radical substitution (addition-elimination) of heterocycles or cyclohydrocarbons units to (E)-β-nitrostyrenes 1 using a common radical initiator benzoyl peroxide. High reactivity and selectivity with wide substrate scope were attained by using this easy methodology. The reactions using easily obtained and one-pot potential starting materials gave excellent trans-selectivity with medium to high yields in all cases. Synthetic utility of this approach has been demonstrated by the preparation of various trans-styryl derivatives.

Phase transfer Wittig reaction with 1,3-dioxolan-2-yl-methyltriphenyl phosphonium salts: An efficient method for vinylogation of aromatic aldehydes

Aldehydes were efficiently transformed into allylic dioxolanes by a Wittig-type reaction, using 1,3-dioxolan-2-yl-methyltriphenylphosphonium bromide under phase transfer conditions. The substituent kinetic effects were studied, and related to Hammett values and electrochemical potentials.