59816-87-4

Basic information

• Product Name: 2-(2-Methylallyl)aniline
• Synonyms: 2-(2-Methylallyl)aniline
• CAS NO: 59816-87-4
• Molecular Formula: C₁₀H₁₃N
• Molecular Weight: 147.21692
• Mol File: 59816-87-4.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(2-Methylallyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-Methylallyl)aniline(59816-87-4)
• EPA Substance Registry System: 2-(2-Methylallyl)aniline(59816-87-4)

Safety Data

• Hazardous Substances Data: 59816-87-4(Hazardous Substances Data)

Usage

Physical state

Pale yellow liquid

Uses

Production of dyes, pharmaceuticals, and agrochemicals

Role

Intermediate in the synthesis of various organic compounds

Potential applications

Development of new drugs and pharmaceutical products

Research interest

Use as a building block in the synthesis of novel organic materials and polymers

Upstream product

• 882788-93-4 N,N-diallyl-2-(2-methylprop-2-en-1-yl)aniline 
• 615-43-0 2-iodophenylamine 
• 73396-92-6 2-iodo-N,N-diallylaniline 
• 22311-55-3 1-(2-methylallyl)-2-nitrobenzene 
• 609-73-4 o-nitroiodobenzene 
• 769-42-6 1,3-dimethylbarbituric acid 
• 98-95-3 nitrobenzene 
• 2973-50-4 2-aminophenylacetonitrile 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 74590-90-2 2,3-dihydro-2-methyl-2-(N-phenylbut-2-en-4-amide)-1H-indole 
• 74590-91-3 N-acryloyl-2-(2-methyl-2-propenyl)aniline 
• 74590-94-6 N-methacryloyl-2-(2-methyl-2-propenyl)aniline 
• 74118-04-0 4-methyl-1,3,4,5-tetrahydro-2H-benzo[b]azepin-2-one 
• 1251853-40-3 C₁₁H₁₅N 
• 71182-59-7 2-isobutylaniline 
• 1573116-63-8 N-cyano-N-[2-(2-methylprop-2-en-1-yl)phenyl]acetamide 
• 1573116-64-9 N-tert-butoxycarbonyl-N-[2-(2-methylprop-2-en-1-yl)phenyl]cyanamide 
• 1573116-48-9 N-[2-(2-methylprop-2-en-1-yl)phenyl]cyanamide 
• 1597592-79-4 N-(2-bromobenzyl)-2-(2-methylallyl)aniline 
• 1627210-80-3 C₁₈H₁₈N₂O₂S 
• 1627210-66-5 C₁₇H₁₅N₃O₄S 
• 1640995-83-0 C₁₇⁽¹³⁾CH₁₈N₂O₂S 
• 1627210-81-4 C₁₈H₁₈N₂O₂S 

Relevant articles and documents

Nickel/Photo-Cocatalyzed Asymmetric Acyl-Carbamoylation of Alkenes

An unprecedented asymmetric acyl-carbamoylation of pendant alkenes tethered on aryl carbamic chlorides with both aliphatic and aromatic aldehydes has been developed via the cooperative catalysis of a chiral nickel-PHOX complex and tetrabutylammonium decatungstate. This reaction represents the first example of merging hydrogen-atom-transfer photochemistry and asymmetric transition metal catalysis in difunctionalization of alkenes. Using this protocol, a variety of oxindoles bearing a challenging quaternary stereogenic center are furnished under mild conditions in highly enantioselective manner.

Palladium-Catalyzed Alkene Carboamination Reactions of Electron-Poor Nitrogen Nucleophiles

Modified reaction conditions that facilitate Pd-catalyzed alkene carboamination reactions of electron-deficient nitrogen nucleophiles are reported. Pent-4-enylamine derivatives bearing N-tosyl or N-trifluoroacetyl groups are coupled with aryl triflates to

Intramolecular aminocyanation of alkenes by N-CN bond cleavage

A metal-free, Lewis acid promoted intramolecular aminocyanation of alkenes was developed. B(C6F5)3 activates N-sulfonyl cyanamides, thus leading to a formal cleavage of the N-CN bonds in conjunction with vicinal addition o