608130-32-1Relevant articles and documents
Synthesis of Phenylcyclopropane-Based Secondary Amine Catalysts and Their Applications in Enamine Catalysis
Kano, Taichi,Maruoka, Keiji,Takeshima, Aika
supporting information, (2019/10/08)
A novel chiral motif based on a phenylcyclopropane scaffold has been designed, and a facile synthetic route to the key intermediate for the synthesis of phenylcyclopropane-based chiral secondary amines has been developed. Newly synthesized chiral amines function as effective catalysts for several asymmetric reactions through enamine intermediates.
Organocatalyst Efficiency in the α-Aminoxylation and α-Hydrazination of Carbonyl Derivatives in Aqueous Media or in a Ball-Mill
Veverková, Eva,Modrocká, Viktória,?ebesta, Radovan
, p. 1191 - 1195 (2017/03/11)
Pyrrolidine-derived organocatalysts have been tested in two types of α-heterofunctionalization reactions in aqueous media or under solvent-free ball-milling conditions. The best results in terms of both activity and enantioselectivity were obtained with O
Highly enantioselective α-aminoxylation reactions catalyzed by isosteviol-proline conjugates in buffered aqueous media
An, Ya-Jie,Wang, Chuan-Chuan,Xu, Yuan-Zhen,Wang, Wei-Juan,Tao, Jing-Chao
experimental part, p. 1123 - 1129 (2012/06/18)
Chiral amphiphilic conjugate catalysts were designed and synthesized by covalently connecting l-proline with an inexpensive natural product, isosteviol. These catalysts demonstrated remarkable efficiency in the asymmetric α-aminoxylation of aldehydes and
