609769-62-2

Basic information

• Product Name: N-benzyl-N-tert-butoxycarbonyl-5-(tert-butyldimethylsiloxy)-1-pentynylamine
• Synonyms: N-benzyl-N-tert-butoxycarbonyl-5-(tert-butyldimethylsiloxy)-1-pentynylamine
• CAS NO: 609769-62-2
• Molecular Weight: 403.637
• Mol File: 609769-62-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-benzyl-N-tert-butoxycarbonyl-5-(tert-butyldimethylsiloxy)-1-pentynylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-N-tert-butoxycarbonyl-5-(tert-butyldimethylsiloxy)-1-pentynylamine(609769-62-2)
• EPA Substance Registry System: N-benzyl-N-tert-butoxycarbonyl-5-(tert-butyldimethylsiloxy)-1-pentynylamine(609769-62-2)

Safety Data

• Hazardous Substances Data: 609769-62-2(Hazardous Substances Data)

Upstream product

• 42116-44-9 N-tert-butoxycarbonylbenzylamine 
• 474022-55-4 [(5-bromo-4-pentyn-1-yl)oxy](tert-butyl)dimethyl-silane 
• 100-46-9 benzylamine 
• 61362-77-4 5-[tert-butyldimethylsilyloxy]pent-1-yne 
• 24424-99-5 di-tert-butyl dicarbonate 

Relevant articles and documents

Reaction of Ynamides with Iminoiodinane-Derived Nitrenes: Formation of Oxazolones and Polyfunctionalized Oxazolidinones

This article describes the reaction of ynamides with metallanitrenes generated in the presence of an iodine(III) oxidant. N-(Boc)-Ynamides are converted to oxazolones via a cyclization reaction. The reaction is mediated by a catalytic dirhodium-bound nitrene species that first behaves as a Lewis acid. The oxazolones can be converted in a one pot manner to functionalized oxazolidinones following a regio- and stereoselective oxyamination reaction with the same nitrene reagent generated in stoichiometric amounts.