622-31-1

Basic information

• Product Name: syn-Benzaldoxime
• Synonyms: (e)-benzaldehyde oxime;(E)-Benzaldoxime;Benzaldehyde (E)-oxime;syn-Benzaldehyde oxime,99+%;syn-Benzaldehyde oxime,93+%;syn-Benzaldehyde oximeBenzaldoxime;trans-Benzaldoxime;(E)-Benzaldehyde oxime 97% (mixture of cis and trans), (Z)-Benzaldehyde oxime
• CAS NO: 622-31-1
• Molecular Formula: C₇H₇NO
• Molecular Weight: 121.14
• EINECS: 213-261-2
• Product Categories: Nitrogen Compounds;Organic Building Blocks;Oximes;Aromatics
• Mol File: 622-31-1.mol
• Article Data: 82

Chemical Properties

• Melting Point: 30-33 °C
• Boiling Point: 104 °C/6 mmHg(lit.)
• Flash Point: 109 °C
• Appearance: /
• Density: 1.1450
• Refractive Index: n20/D 1.591(lit.)
• Storage Temp.: 2-8°C
• Solubility: methanol: soluble0.1g/mL, clear
• PKA: 10.80±0.70(Predicted)
• CAS DataBase Reference: syn-Benzaldoxime(CAS DataBase Reference)
• NIST Chemistry Reference: syn-Benzaldoxime(622-31-1)
• EPA Substance Registry System: syn-Benzaldoxime(622-31-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 622-31-1(Hazardous Substances Data)

Usage

Description

syn-Benzaldoxime, also known as (E)-benzaldehyde oxime, is a chemical compound derived from the reduction of (E)-benzaldehyde at various pH levels. It is characterized by its light yellow liquid appearance after melting and possesses antioxidant properties.

Uses

1. Used in Pharmaceutical Industry:
syn-Benzaldoxime is used as an antioxidant for stabilizing and preserving pharmaceutical products, preventing oxidation and degradation, which can lead to loss of potency or efficacy.
2. Used in Chemical Industry:
syn-Benzaldoxime is used as a chemical intermediate for the synthesis of various compounds, taking advantage of its reactivity and unique chemical properties.
3. Used in Cosmetic Industry:
syn-Benzaldoxime is used as an antioxidant in the cosmetic industry to extend the shelf life of products and protect them from oxidative damage, ensuring their safety and effectiveness.
4. Used in Food Industry:
syn-Benzaldoxime is used as an additive in the food industry to prevent spoilage and maintain the quality of products by neutralizing harmful free radicals and preventing oxidation.
5. Used in Research and Development:
syn-Benzaldoxime is used as a research compound for studying its chemical properties, reactivity, and potential applications in various fields, including pharmaceuticals, materials science, and environmental science.

Upstream product

• 13591-25-8 dibenzylidene-diazoxane-N-oxide 
• 121-68-6 dithiobenzoic acid 
• 6725-34-4 thiobenzaldehyde 
• 16118-22-2 benzylidenamine 
• 18322-86-6 benzaldoxime benzoate 
• 80055-49-8 (E)-benzaldehyde O-acetyl oxime 
• 880143-20-4 benzaldehyde-(O-ethoxycarbonyl-seqtrans-oxime ) 
• 91737-49-4 (Z)-benzaldehyde-(O-phenylcarbamoyl oxime ) 
• 4657-12-9 sodium hydroxy(phenyl)methanesulfonate 
• 100-52-7 benzaldehyde 
• 536-57-2 p-toluene sulfinic acid 
• 70-55-3 toluene-4-sulfonamide 
• 57267-72-8 toluene-4-sulfinic acid ; ammonium salt 
• 622-30-0 N-benzyl hydroxylalmine 

Downstream Products

• 10229-54-6 benzaldehyde-(O-methyl-seqcis-oxime ) 
• 100-47-0 benzonitrile 
• 17966-68-6 N-benzoylaspartic acid 
• 7064-07-5 3-phenyl-5-acetoxy-4,5-dihydroisoxazole 
• 4124-42-9 monoammonium para-toluenesulfonate 
• 70-55-3 toluene-4-sulfonamide 
• 489-98-5 picramide 
• 100-52-7 benzaldehyde 
• 29076-84-4 propiophenone-imine 
• 2810-72-2 N-phenyl-[1-(ethyl)-propyl]amine 
• 62-53-3 aniline 
• 1865-12-9 N-(diphenylmethyl)aniline 
• 13591-25-8 dibenzylidene-diazoxane-N-oxide 
• 115294-76-3 benzaldehyde-[O-(3,3-dichloro-2-methyl-allyl)-oxime ] 

Relevant articles and documents

Novel oxime derivative and application thereof in agriculture

The present invention relates to a novel oxime derivative and application thereof in agriculture. The novel oxime derivative has a structure represented by formula (I), wherein R, R, R, R and R are each independently hydrogen, fluorine, chlorine or the like, A is shown as the specification, wherein R and R are each independently hydrogen, C1-4 alkyl group, phenyl group or the like, R is C1-4 alkoxy group or the like, and R is hydrogen or C1-4 alkyl group. The novel oxime derivative disclosed by the invention is novel in structure and simple in synthesis process, and has an excellent control effect on plant diseases, particularly cucumber downy mildew.

Selective Carbon-Carbon Bond Amination with Redox-Active Aminating Reagents: A Direct Approach to Anilines?

Amines are among the most fundamental motifs in chemical synthesis, and the introduction of amine building blocks via selective C—C bond cleavage allows the construction of nitrogen compounds from simple hydrocarbons through direct skeleton modification. Herein, we report a novel method for the preparation of anilines from alkylarenes via Schmidt-type rearrangement using redox-active amination reagents, which are easily prepared from hydroxylamine. Primary amines and secondary amines were prepared from corresponding alkylarenes or benzyl alcohols under mild conditions. Good compatibility and valuable applications of the transformation were also displayed.

Visible-light mediated stereospecific C(sp2)-H difluoroalkylation of (Z)-aldoximes

A visible light mediated stereospecific C(sp2)-H difluoroalkylation of (Z)-aldoximes to (E)-difluoroalkylated ketoximes has been described. In this reaction, (hetero)-aromatic and aliphatic difluoroalkylated ketoximes could be obtained with the retention of the configuration of the starting aldoximes. A preliminary mechanism study showed that a difluoromethyl radicalviaan SET pathway was involved.