623-25-6 Usage
Chemical Properties
white to light yellow crystal powde
Uses
Different sources of media describe the Uses of 623-25-6 differently. You can refer to the following data:
1. α,α′-Dichloro-p-xylene is a monomer used in preparation of poly(p-phenylene vinylene(PPV) nanotubes and nanorods by chemical vapor deposition (CVD) polymerization method 1 . α,α′-Dichloro-p-xylene was used in a study to investigate the effect of CVD monomer selection and reaction conditions on the resulting PPV polymer layer composition and luminescence properties 2 .
2. p-Xylylene dichloride is a monomer used in preparation of poly(p-phenylene vinylene(PPV) nanotubes and nanorods by chemical vapor deposition (CVD) polymerization method. It was used in a study to investigate the effect of CVD monomer selection and reaction conditions on the resulting PPV polymer layer composition and luminescence properties.
General Description
α,α′-Dichloro-p-xylene undergoes phase transfer catalysed polycondensation with t-butylcyanoacetate to form carbon-carbon chain polymer.
Flammability and Explosibility
Notclassified
Purification Methods
Crystallise the xylene from *benzene and dry it under vacuum. [Beilstein 5 IV 967.]
Check Digit Verification of cas no
The CAS Registry Mumber 623-25-6 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,2 and 3 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 623-25:
(5*6)+(4*2)+(3*3)+(2*2)+(1*5)=56
56 % 10 = 6
So 623-25-6 is a valid CAS Registry Number.
623-25-6Relevant articles and documents
p-Phenylenebismethylene: Characterization, calculation, and conversion to a conjugated bis-carbonyloxide [10]
Subhan,Rempala,Sheridan
, p. 11528 - 11529 (1998)
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NMP-mediated chlorination of aliphatic alcohols with aryl sulfonyl chloride for the synthesis of alkyl chlorides
Zheng, Dagui,Mao, Liu-Liang,Zhu, Xian-Hong,Zhou, An-Xi
supporting information, p. 2793 - 2800 (2018/11/06)
NMP-mediated chlorination of aliphatic alcohols has been developed for the synthesis of alkyl chlorides. This facile, efficient and practical approach used simple and readily available aryl sulfonyl chlorides as the chlorination reagent for the construction of C–Cl bond in good to excellent yields with mild conditions and broad substrate scope.
Improved Halogenation of Methyl Aromatics and Methyl Heteroaromatics: Unexpected Reactivity of Tetrahalogeno-diphenylglycolurils
Moretti, Florian,Poisson, Guillaume,Marsura, Alain
, p. 173 - 183 (2016/05/19)
1,3,4,6-Tetrachloro (TCDGU) and 1,3,4,6-tetrabromo-3α,6α-diphenylglycolurils smooth halogen oxidizers have been exploited in a new direction as reagents for free radical substitution toward some N-halosuccinimide nonreactive bis-heterocycles. An unexpected selectivity and reactivity were observed with methyl benzenes, methyl heterocycles, and methyl-bis-heterocycles of interest. A chemometric study has been performed to optimize five independent factors of the chlorination reaction with TCDGU. The predictive model was established either for the halogenation conversion and the ratio of monochlorination.