62751-30-8

Basic information

• Product Name: 2-Pentenoic acid, 4-methyl-3-phenyl-, ethyl ester, (Z)-
• CAS NO: 62751-30-8
• Molecular Formula: C14H18O2
• Molecular Weight: 218.296
• Mol File: 62751-30-8.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: 2-Pentenoic acid, 4-methyl-3-phenyl-, ethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentenoic acid, 4-methyl-3-phenyl-, ethyl ester, (Z)-(62751-30-8)
• EPA Substance Registry System: 2-Pentenoic acid, 4-methyl-3-phenyl-, ethyl ester, (Z)-(62751-30-8)

Safety Data

• Hazardous Substances Data: 62751-30-8(Hazardous Substances Data)

Upstream product

• 2216-94-6 phenylpropynoic acid ethyl ester 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 611-70-1 phenyl isopropyl ketone 
• 18819-66-4 (Z)-3-chloro-3-phenyl-2-propenoic acid 
• 18819-63-1 (E)-3-chloro-3-phenyl-2-propenoic acid 
• 38491-47-3 ethyl 4-methylpent-2-ynoate 
• 98-80-6 phenylboronic acid 
• 55164-20-0 ethyl-(E)-3-chloro-3-phenyl-2-propenoate 
• 55164-19-7 ethyl-(Z)-3-chloro-3-phenyl-2-propenoate 
• 591-50-4 iodobenzene 
• 15790-86-0 ethyl-4-methyl-2-(E)-penteneoate 

Downstream Products

• 77921-03-0 (E)-4-methyl-3-phenyl-2-pentenoic acid 
• 309270-99-3 (E)-4-methyl-3-phenyl-2-penten-1-ol 
• 309270-97-1 (Z)-4-methyl-3-phenyl-2-penten-1-ol 
• 914400-07-0 (E)-N-methoxy-N,4-dimethyl-3-phenylpent-2-enamide 
• 876953-21-8 (E)-5-methyl-4-phenyl-3-hexen-2-one 
• 120609-18-9 (+/-)-5-methyl-4-phenylhexan-2-one 
• 435269-66-2 (S)-5-methyl-4-phenylhexan-2-one 
• 162239-77-2 (R)-5-methyl-4-phenyl-hexan-2-one 
• 1019003-37-2 (R)-ethyl 4-methyl-3-phenylpentanoate 

Relevant articles and documents

Enantioselective epoxidation of β,β-disubstituted enamides with a manganese catalyst and aqueous hydrogen peroxide

Enantioselective epoxidation of β,β-disubstituted enamides with aqueous hydrogen peroxide and a novel manganese catalyst is described. Epoxidation is stereospecific and proceeds fast under mild conditions. Amides are disclosed as key functional groups to enable high enantioselectivity.

The synthesis of non-racemic β-alkyl-β-aryl-disubstituted allyl alcohols and their transformation into allylamines and amino acids bearing a quaternary stereocenter

A synthesis of non-racemic β-alkyl-β-aryl allyl alcohols and their transformation into allylamines bearing a quaternary stereogenic center is reported. The allyl alcohols were prepared either by Cu-catalyzed enantioselective reduction of enones or by sequ

Ruthenium-catalyzed oxidation of allyl alcohols with intermolecular hydrogen transfer: Synthesis of α,β-unsaturated carbonyl compounds

Ruthenium-catalyzed oxidation of multisubstituted allyl alcohols in the presence of benzaldehyde gives enals or enones in good yields. Unlike the commonly reported ruthenium-catalyzed isomerization reaction of allyl alcohols to give saturated ketones, an intermolecular rather than intramolecular hydrogen transfer is involved in this transformation. This reaction offers an efficient, mild, and high-yielding method for the preparation of substituted α,β-unsaturated compounds.