62839-71-8

Basic information

• Product Name: Benzene, 1-decenyl-, (E)-
• CAS NO: 62839-71-8
• Molecular Formula: C16H24
• Molecular Weight: 216.367
• Mol File: 62839-71-8.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Benzene, 1-decenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-decenyl-, (E)-(62839-71-8)
• EPA Substance Registry System: Benzene, 1-decenyl-, (E)-(62839-71-8)

Safety Data

• Hazardous Substances Data: 62839-71-8(Hazardous Substances Data)

Upstream product

• 124-19-6 nonan-1-al 
• 144708-17-8 2-<(phenylmethyl)sulfonyl>pyrimidine 
• 872-05-9 1-Decene 
• 909413-25-8 6-(tert-butyl)-12-phenyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine 
• 2404-44-6 1,2-Epoxydecane 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 79930-37-3 1-methoxy-1-decene 
• 100-58-3 phenylmagnesium bromide 
• 57074-37-0 (Z)-4-decen-1-ol 
• 629-27-6 1-Iodooctane 
• 5418-11-1 phenyl styryl sulfone 
• 81-07-2 saccharin 
• 37952-93-5 N-benzoyl saccharin 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Pd-catalyzed oxidative Heck-type arylation of vinyl ketones, alkenes, and acrylates with Sb-aryl-tetrahydrodibenz[c,f][1,5]azastibocines

The Pd-catalyzed cross-coupling reactions of Sb-aryl-1,5-azastibocines with alkenes are described. The reactions of azastibocines with alkenes such as vinyl ketones, alkenes, and acrylates in the presence of 10 mol% PdCl2 at 80 °C in DMA under aerobic conditions produced Heck adducts in moderate-to-excellent yields. Single-crystal X-ray and NMR analysis revealed that the aryl donors in this reaction, the Sb-aryl-1,5-azastibocines, are hypervalent compounds that display N–Sb intramolecular non-bonding interaction. These are the first examples of Pd-catalyzed Heck-type arylations using heterocyclic hypervalent organoantimony compounds. Although the reactions proceeded efficiently with the azastibocines, they hardly progressed with trivalent and pentavalent triarylantimony reagents.

Palladium/Light induced radical alkenylation and allylation of alkyl iodides using alkenyl and allylic sulfones

Alkenylation and allylation of alkyl iodides with alkenyl and allyl sulfones, respectively, took place under Pd/photoirradiation system. The initial alkyl radical, derived from a single electron transfer between Pd(0) and RI, underwent the title transformations. Pd(0) was regenerated through a reductive elimination of PhSO2PdI, which is formed by the combination of the sulfonyl radical and the palladium radical. The addition of water was effective, presumably by pushing the equilibrium through hydrolysis of PhSO2I.

N-Acylsaccharins as Amide-Based Arylating Reagents via Chemoselective N-C Cleavage: Pd-Catalyzed Decarbonylative Heck Reaction

Palladium-catalyzed decarbonylative Heck reaction of amides by chemoselective N-C activation using N-acylsaccharins as coupling partners has been accomplished. These studies represent only the second example of amide-Heck reactions reported to date. A broad range of electronically diverse amide and olefin coupling partners is amenable to this transformation. Orthogonal site-selective Heck cross-couplings by C-Br/N-C cleavage and mechanistic studies are reported. This report introduces readily available, bench-stable, cheap, and benign N-acylsaccharins as aryl transfer reagents to access versatile aryl-metal intermediates.