6328-72-9Relevant articles and documents
Linear Free Energy Relationship in Naphthalene System: Kinetics of Hydrolysis of 4-Substituted 1-Naphthalenesulphonyl Chlorides
Perumal, S.,Selvaraj, S.,Viswanathan, T. K.,Arumugam, N.
, p. 436 - 438 (2007/10/02)
The kinetics of hydrolysis of several 4-substituted 1-naphthalenesulphonyl chlorides have been studied in aqueous acetone at three temperatures.The reaction is first order in sulphonyl chloride.Presence of electron-withdrawing substituents in the naphthyl ring enhances the rate while that of opposite ones retards it.The small ρ-values obtained in the correlation analysis using the Hammett and dual substituent parameter equations are consistent with either an SN2 or an SAN mechanism.