6372-57-2

Basic information

• Product Name: rel-(2α*,3α*)-1-Benzyl-2-benzoyl-3-phenylaziridine
• Synonyms: rel-(2α*,3α*)-1-Benzyl-2-benzoyl-3-phenylaziridine
• CAS NO: 6372-57-2
• Molecular Formula: C₂₂H₁₉NO
• Molecular Weight: 313.3924
• Mol File: 6372-57-2.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 454.2°Cat760mmHg
• Flash Point: 171.3°C
• Appearance: /
• Density: 1.187g/cm³
• Vapor Pressure: 1.94E-08mmHg at 25°C
• Refractive Index: 1.648
• CAS DataBase Reference: rel-(2α*,3α*)-1-Benzyl-2-benzoyl-3-phenylaziridine(CAS DataBase Reference)
• NIST Chemistry Reference: rel-(2α*,3α*)-1-Benzyl-2-benzoyl-3-phenylaziridine(6372-57-2)
• EPA Substance Registry System: rel-(2α*,3α*)-1-Benzyl-2-benzoyl-3-phenylaziridine(6372-57-2)

Safety Data

• Hazardous Substances Data: 6372-57-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C22H19NO/c24-22(19-14-8-3-9-15-19)21-20(18-12-6-2-7-13-18)23(21)16-17-10-4-1-5-11-17/h1-15,20-21H,16H2

Upstream product

• 611-91-6 trans-2,3-dibromo-1,3-diphenylpropan-1-one 
• 100-46-9 benzylamine 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 294886-82-1 2-benzyl-3,5-diphenyl-2,3-dihydro-isoxazole 
• 3376-26-9 N-Benzylidenbenzylamin-N-oxid 
• 32147-20-9 (Z)-2-bromo-1,3-diphenylprop-2-en-1-one 
• 611-91-6 2,3-dibromo-1,3-diphenylpropane-1-one 
• 294886-74-1 N-benzyl-N-(1,3-diphenylprop-2-yn-1-yl)hydroxylamine 
• 3376-26-9 N-Benzylidenebenzylamine N-oxide 
• 536-74-3 phenylacetylene 

Downstream Products

• 6628-56-4 (+/-)-benzyl-(1,3,5t-triphenyl-4,5-dihydro-1H-pyrazol-4r-yl)-amine 
• 2183-27-9 1,3,5-triphenyl-1H-pyrazole 
• 279690-85-6 Dimethyl N-benzyl-N-(2-oxo-2-phenylethyl)amino-1-phenylmethylphosphonate 
• 1258314-43-0 C₃₃H₂₉NO₂ 
• 1353722-06-1 benzyl 1-benzyl-2-methyl-4-phenyl-1H-pyrrole-3-carboxylate 
• 1353722-09-4 benzyl 1-benzyl-5-(1'-hydroxy-1'-phenylmethyl)-2-methyl-4-phenyl-1H-pyrrole-3-carboxylate 
• 1353722-08-3 benzyl 1-benzyl-2-ethyl-4-phenyl-1H-pyrrole-3-carboxylate 
• 1353722-07-2 benzyl 1,2-dibenzyl-4-phenyl-1H-pyrrole-3-carboxylate 

Relevant articles and documents

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Oxygenation of Simple Olefins through Selective Allylic C?C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes

A novel metal-free allylic C?C σ-bond cleavage of simple olefins to give valuable cinnamyl aldehydes is reported. 1,2-Aryl or alkyl migration through allylic C?C bond cleavage occurs in this transformation, which is assisted by an alkyl azide reagent. This method enables O-atom incorporation into simple unfunctionalized olefins to construct cinnamyl aldehydes. The reaction features simple hydrocarbon substrates, metal-free conditions, and high regio- and stereoselectivity.

Selective transformation of N-(propargylic)hydroxylamines into 4-isoxazolines and acylaziridines promoted by metal salts

Cyclization of N-(propargylic)hydroxylamines catalyzed by AgBF4 afforded the corresponding 4-isoxazolines in good yields. Copper salts were found to promote the further transformation to acylaziridines. The combined use of AgBF4 and CuCl realiz