63975-59-7

Basic information

• Product Name: (R)-(-)-10-METHYL-1(9)-OCTAL-2-ONE
• Synonyms: R(-)-4A-METHYL-2,3,4,4A,5,6,7,8-OCTAHYDRO-2-NAPHTHALENONE;(R)-(-)-4,4A,5,6,7,8-HEXAHYDRO-4A-ALPHA-METHYL-2(3H)-NAPHTHALENONE;(R)-(-)-4,4A,5,6,7,8-HEXAHYDRO-4A-METHYL-2(3H)-NAPHTHALENONE;(R)-(-)-10-METHYL-1(9)-OCTAL-2-ONE;4a-Methyl-4,4a,5,6,7,8-hexahydro-2(3H)-naphthalenone;R-(-)-4,4a,5,6,7,8-Hexahydro-4a-methyl-2(3H)-naphthalinone;2(3H)-Naphthalenone, 4,4a,5,6,7,8-hexahydro-4a-methyl-, (4aR)-;(4AR)-4A-METHYL-3,4,5,6,7,8-HEXAHYDRONAPHTHALEN-2-ONE
• CAS NO: 63975-59-7
• Molecular Formula: C₁₁H₁₆O
• Molecular Weight: 164.24
• Mol File: 63975-59-7.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 155 °C17 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.018 g/mL at 20 °C(lit.)
• Vapor Pressure: 0.00396mmHg at 25°C
• Refractive Index: n20/D 1.525(lit.)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: (R)-(-)-10-METHYL-1(9)-OCTAL-2-ONE(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-10-METHYL-1(9)-OCTAL-2-ONE(63975-59-7)
• EPA Substance Registry System: (R)-(-)-10-METHYL-1(9)-OCTAL-2-ONE(63975-59-7)

Safety Data

• Hazard Codes: Xn
• Statements: 36-20/21/22
• Safety Statements: 23-24/25
• WGK Germany: 3
• F: 10-23
• Hazardous Substances Data: 63975-59-7(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS TO YELLOW LIQUID

InChI:InChI=1/C11H16O/c1-11-6-3-2-4-9(11)8-10(12)5-7-11/h8H,2-7H2,1H3/t11-/m1/s1

Upstream product

• 108-75-8 2,4,6-trimethyl-pyridine 
• 2530-21-4 3t-Brom-4-ar-methyl(8atH)-decalon-(2) 
• 91306-30-8 (R)-(+)-2-methyl-2-(3-oxobutyl)cyclohexanone 
• 4707-07-7 8aα-hydroxy-4aα-methyloctahydronaphthalen-2(1H)-one 
• 119489-83-7 (R)-(-)-4,4a,5,6-tetrahydro-4aβ-methyl-2(3H)-naphthalenone 
• 78-94-4 methyl vinyl ketone 
• 583-60-8 2-Methylcyclohexanone 
• 1728-38-7 methyl enol ether of 2-methylcyclohexanone 
• 115692-63-2 (R)-(+)-2-(trans-but-2-enyl)-2-methylcyclohexanone 
• 13567-75-4 (4aR,7R,8aR)-8a-hydroxy-7-isopropenyl-4a-methyloctahydro-2(1H)-naphthalenone 
• 119489-80-4 1-((2R,4aR,7S,8aR)-7,8a-Dihydroxy-4a-methyl-decahydro-naphthalen-2-yl)-ethanone 
• 119489-86-0 Acetic acid (2R,4aR)-4a-methyl-7-oxo-1,2,3,4,4a,5,6,7-octahydro-naphthalen-2-yl ester 
• 119489-82-6 (2S,4aR,7R,8aR)-7-acetoxy-8a-hydroxy-4a-methyloctahydro-2(1H)-naphthalenone 
• 119489-79-1 (2S,4aR,7R,8aR)-7-isopropenyl-4a-methyldecahydronaphthalene-2,8a-diol 

Downstream Products

• 372490-64-7 (R)-4,4a,5,6,7,8-hexahydro-3-[4'(2'-ketobutyl)]-4aβ-methyl-2(3H)-naphthalenone 
• 745-14-2 9-methyl-1,2,6,7,8,9-hexahydronaphthalene-3(5H)-one 2,4-dinitrophenylhydrazone 

Relevant articles and documents

Highly enantioselective [2+2]-cycloaddition reactions catalyzed by a chiral aluminum bromide complex

Enantioselective [2+2]-cycloaddition pathways to chiral cyclobutanes are rare and not generally utilized for synthesis. A new cycloaddition reaction of vinyl ethers with trifluoroethyl acrylate in the presence of a catalytic amount of chiral oxazaborolidi

Synthesis of the 5-demethyl-6-deoxy analogue of sporogen AO-1, a sporogenic substance of Aspergillus oryzae

Sporogen AO-1 is a sporulation-stimulating substance isolated from Aspergillus oryzae. We speculated that ring B would be important for the activity and designed a compound without functional groups in ring A. We synthesized the compound from 2-methylcycl

(R)-(-)-10-methyl-1(9)-octal-2-one

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