63982-24-1

Basic information

• Product Name: N-Phenethylcarbamic acid isopropyl ester
• Synonyms: N-Phenethylcarbamic acid isopropyl ester
• CAS NO: 63982-24-1
• Molecular Formula: C₁₂H₁₇NO₂
• Molecular Weight: 207.27
• Mol File: 63982-24-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 329.4°C at 760 mmHg
• Flash Point: 153°C
• Appearance: /
• Density: 1.031g/cm³
• Vapor Pressure: 0.000178mmHg at 25°C
• Refractive Index: 1.505
• CAS DataBase Reference: N-Phenethylcarbamic acid isopropyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-Phenethylcarbamic acid isopropyl ester(63982-24-1)
• EPA Substance Registry System: N-Phenethylcarbamic acid isopropyl ester(63982-24-1)

Safety Data

• Hazardous Substances Data: 63982-24-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H17NO2/c1-10(2)15-12(14)13-9-8-11-6-4-3-5-7-11/h3-7,10H,8-9H2,1-2H3,(H,13,14)

Upstream product

• 38427-90-6 N-(t-butoxycarbonyl)phenethylamine 
• 546-68-9 titanium(IV)isopropoxide 
• 6970-83-8 ethyl-N-(2-phenethyl)carbamate 
• 70867-38-8 benzyl (2-phenylethyl)carbamate 
• 108-23-6 isopropyl chloroformate 
• 64-04-0 phenethylamine 
• 51729-83-0 methyl 1-methylethyl carbonate 
• 6482-34-4 bis-2-propyl carbonate 
• 616-38-6 carbonic acid dimethyl ester 
• 546-68-9 titanium(IV) isopropylate 
• 81682-58-8 Oxalic acid N-(2-phenylethyl)monoamide 
• 67-63-0 isopropyl alcohol 

Relevant articles and documents

Urethanes synthesis from oxamic acids under electrochemical conditions

Urethane synthesis via oxidative decarboxylation of oxamic acids under mild electrochemical conditions is reported. This simple phosgene-free route to urethanes involves an in situ generation of isocyanates by anodic oxidation of oxamic acids in an alcoholic medium. The reaction is applicable to a wide range of oxamic acids, including chiral ones, and alcohols furnishing the desired urethanes in a one-pot process without the use of a chemical oxidant.

Synthesis of carbamates from amines and dialkyl carbonates: Influence of leaving and entering groups

A number of carbamates were synthesised through a halogen-free process by reacting amines with symmetrical and unsymmetrical carbonates. The results obtained showed a specific trend of preferred leaving groups (in the dialkyl carbonates) depending on whether a catalyst or a base was used. On the other hand, investigations conducted on the preferred entering groups (amines) for the synthesis of carbamates showed the same trend regardless of whether a catalyst or a base was used. Finally, in accordance with the results obtained, it was possible to synthesise sterically hindered carbamates in high yield by transesterification of methyl carbamate with a sterically hindered alcohol. Georg Thieme Verlag Stuttgart New York.

Facile and Selective O-Alkyl Transesterification of Primary Carbamates with Titanium(IV) Alkoxides

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