64394-08-7Relevant articles and documents
Nucleophilic substitution reactions of benzyl- and diphenylmethylphosphonamidic chlorides with amines: Competition between the usual SN2(P) mechanism and elimination-addition with an alkylideneoxophosphorane (phosphene) intermediate
Harger, Martin J. P.
, p. 41 - 47 (2007/10/03)
The substitution reaction of PhCH2P(O)(NMe2)Cl with Me2NH or Et2NH in CHCI3 is very sensitive to the bulk of the nucleophile (≥ 200 times slower with Et2NH), affords only the product derive