6528-19-4Relevant articles and documents
Reactions of isomeric arylchloropyruvates and glycidates with hydrazines
Mamedov,Mustakimova,Gubaidullin,Litvinov,Levin
, p. 694 - 702 (2005)
Reactions of arylchloropyruvic acids esters with aryl- and hetarylhydrazines give rise to pyrazolinedione hydrazones as a result of a tandem condensation of the substituted hydrazines with arylchloropyruvates. In contrast to this process in reaction with hydrazine hydrate a ready reduction unexpectedly occurs by Kizhner-Wolff mechanism affording 3- hydroxydihydrocinnamic acid hydrazide as the principal product. The isomeric arylglycidate reacts along the same pattern. 2005 Pleiades Publishing, Inc.