65523-28-6Relevant articles and documents
Torsional distortions in trimesitylsilanes and trimesitylgermanes
Lambert, Joseph B.,Stern, Charlotte L.,Zhao, Yan,Tse, Winston C.,Shawl, Catherine E.,Lentz, Kirk T.,Kania, Lidia
, p. 21 - 31 (2007/10/03)
The crystal structures have been solved for allyltrimesitylsilane (3), trimesitylsilane (4), and trimesitylgermane (5). Steric congestion caused by the three mesityl groups causes some lengthening of the Si-C and Ge-C bonds. The C-Si-C and C-Ge-C bond ang
UEBER STERISCH GEHINDERTE FREIE RADIKALE XI. DIE ERSTE REVERSIBLE THERMISCHE DISSOZIATION VON DISILANEN R3Si-SiR3 ZU SILYLRADIKALEN R3Si. UND VON DIGERMANEN R3Ge-GeR3 ZU GERMYLRADIKALEN R3Ge.
Neumann, Wilhelm P.,Schultz, Klaus-Dieter,Vieler, Robert
, p. 179 - 192 (2007/10/02)
The Si-Si bond in hexamesityldisilane dissociates reversibly even between -60 and -32 deg C (ΔHdiss 19.0 +/- 2 kcal mol-1) and the Ge-Ge bond in hexamesityldigermane reversibly between -12 and +53 deg C (ΔHdiss 20.7 +/- 2