66367-70-2Relevant articles and documents
Ultra-Fast Molecular Rotors within Porous Organic Cages
Hughes, Ashlea R.,Brownbill, Nick J.,Lalek, Rachel C.,Briggs, Michael E.,Slater, Anna G.,Cooper, Andrew I.,Blanc, Frédéric
, p. 17217 - 17221 (2017)
Using variable temperature 2H static NMR spectra and 13C spin-lattice relaxation times (T1), we show that two different porous organic cages with tubular architectures are ultra-fast molecular rotors. The central para-phen
Ultrafast Molecular Rotors and Their CO2 Tuning in MOFs with Rod-Like Ligands
Bracco, Silvia,Castiglioni, Fabio,Comotti, Angiolina,Galli, Simona,Negroni, Mattia,Maspero, Angelo,Sozzani, Piero
, p. 11210 - 11215 (2017/08/26)
A metal organic framework (MOF) engineered to contain in its scaffold rod-like struts featuring ultrafast molecular rotors showed extremely rapid 180 ° flip reorientation with rotational rates of 1011 Hz at 150 K. Crystal-pore accessibility of
