866139-54-0Relevant articles and documents
Ultrafast Molecular Rotors and Their CO2 Tuning in MOFs with Rod-Like Ligands
Bracco, Silvia,Castiglioni, Fabio,Comotti, Angiolina,Galli, Simona,Negroni, Mattia,Maspero, Angelo,Sozzani, Piero
, p. 11210 - 11215 (2017)
A metal organic framework (MOF) engineered to contain in its scaffold rod-like struts featuring ultrafast molecular rotors showed extremely rapid 180 ° flip reorientation with rotational rates of 1011 Hz at 150 K. Crystal-pore accessibility of
Ionic rotors. Preparation, structure, and dynamic solid-state 2D NMR study of the 1,4-diethynylbenzenebis(triphenylborate) dianion
Gardinier, James R.,Pellechia, Perry J.,Smith, Mark D.
, p. 12448 - 12449 (2007/10/03)
The reaction between p-(LiC2)2C6H4 (generated in situ from butyllithium and dialkynylbenzene) and 2 equiv of BPh3 affords high yields of [Li(THF)4]2[p-(Ph3BC2/su