66644-67-5

Basic information

• Product Name: ETHYL 2-METHYLBENZOYLFORMATE
• Synonyms: ETHYL 2-METHYLBENZOYLFORMATE;2-Methyl-oxo-benzeneacetic acid ethyl ester
• CAS NO: 66644-67-5
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.21
• Mol File: 66644-67-5.mol
• Article Data: 25

Chemical Properties

• Boiling Point: 289.745°C at 760 mmHg
• Flash Point: 127.236°C
• Appearance: /
• Density: 1.106g/cm³
• Vapor Pressure: 0.002mmHg at 25°C
• Refractive Index: 1.512
• CAS DataBase Reference: ETHYL 2-METHYLBENZOYLFORMATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 2-METHYLBENZOYLFORMATE(66644-67-5)
• EPA Substance Registry System: ETHYL 2-METHYLBENZOYLFORMATE(66644-67-5)

Safety Data

• Hazardous Substances Data: 66644-67-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H12O3/c1-3-14-11(13)10(12)9-7-5-4-6-8(9)2/h4-7H,3H2,1-2H3

Upstream product

• 64-17-5 ethanol 
• 5955-73-7 2-methylbenzoyl cyanide 
• 932-31-0 ortho-tolylmagnesium bromide 
• 95-92-1 oxalic acid diethyl ester 
• 6957-89-7 Ethyl dichloro-(ethoxy)-acetate 
• 108-88-3 toluene 
• 4755-77-5 Ethyl oxalyl chloride 
• 600173-06-6 2-ethoxycarbonyl-2-hydroxy-2-(2-methylphenyl)-acetonitrile 
• 16419-60-6 2-Methylphenylboronic acid 
• 623-49-4 ethyl cyanoformate 
• 529-20-4 2-methylphenyl aldehyde 
• 933-88-0 ortho-toluoyl chloride 
• 33872-80-9 o-tolyl magnesium chloride 
• 62281-72-5 ethyl hydroxy(2-methylphenyl)acetate 

Downstream Products

• 62281-72-5 ethyl hydroxy(2-methylphenyl)acetate 
• 62281-64-5 o-Tolyl-triethylsilanyloxy-acetic acid ethyl ester 
• 85905-80-2 (Dibutyl-ethyl-silanyloxy)-o-tolyl-acetic acid ethyl ester 
• 85905-84-6 o-Tolyl-triisobutylsilanyloxy-acetic acid ethyl ester 
• 85905-72-2 [(Ethoxycarbonyl-o-tolyl-methoxy)-phenyl-silanyloxy]-o-tolyl-acetic acid ethyl ester 
• 85905-73-3 C₃₉H₄₄O₉Si 
• 52182-19-1 2,2'-dimethyl-benzilic acid ethyl ester 
• 211044-11-0 (S)-1-(2-methylphenyl)ethane-1,2-diol 
• 139093-41-7 (R)-1-(2-methylphenyl)ethane-1,2-diol 
• 125602-39-3 ethyl 2-(bromomethyl)benzoylformate 
• 1086108-78-2 (Z)-ethyl 2-(4-methoxyphenylimino)-2-o-tolylacetate 
• 1068161-63-6 C₁₇H₁₈N₂O₂ 
• 1220306-89-7 C₁₄H₁₅NO₃ 
• 1254939-24-6 ethyl 2-hydroxy-2-o-tolylpent-4-enoate 

Relevant articles and documents

Electrochemical two-electron oxygen reduction reaction (ORR) induced aerobic oxidation of α-diazoesters

Electrochemical oxygen reduction reaction (ORR) is a powerful tool for introducing oxygen functional groups in synthetic chemistry. However, compared with the well-developed one-electron oxygen reduction process, the applications of two-electron oxygen re

Photoinduced Diverse Reactivity of Diazo Compounds with Nitrosoarenes

A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and a formal [2 + 2] cycloaddition is reported. Nitosoarene has been exploited as a mild oxygen source to oxidize an in situ generated carbene intermediate under visible-light irradiation. UV-light-mediated in situ generated ketenes react with nitosoarenes to deliver oxazetidine derivatives. These operationally simple processes exemplify a transition-metal-free and catalyst-free protocol to give structurally diverse α-ketoesters or oxazetidines.

Metal-Free Oxidative Esterification of Ketones and Potassium Xanthates: Selective Synthesis of α-Ketoesters and Esters

A novel and efficient oxidative esterification for the selective synthesis of α-ketoesters and esters has been developed under metal-free conditions. In the protocol, various α-ketoesters and esters are available in high yields from commercially available ketones and potassium xanthates. Mechanistic studies have proven that potassium xanthate not only promotes oxidative esterification but also provides an alkoxy moiety for the reaction, which involves the cleavage and reconstruction of C-O bonds.