66680-86-2

Basic information

• Product Name: 2-METHYLPROPENE-1-TRIBUTYLSTANNANE
• Synonyms: 2-METHYLPROPENE-1-TRIBUTYLSTANNANE;2-Methyl-1-propenyl-1-tributylstannane;(2-Methylprop-1-en-1-yl)tributylstannane;Stannane, tributyl(2-methyl-1-propenyl)-
• CAS NO: 66680-86-2
• Molecular Formula: C₁₆H₃₄Sn
• Molecular Weight: 345.155
• Product Categories: Stannanes
• Mol File: 66680-86-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 330.124°C at 760 mmHg
• Flash Point: 157.636°C
• Appearance: /
• Vapor Pressure: 0mmHg at 25°C
• CAS DataBase Reference: 2-METHYLPROPENE-1-TRIBUTYLSTANNANE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYLPROPENE-1-TRIBUTYLSTANNANE(66680-86-2)
• EPA Substance Registry System: 2-METHYLPROPENE-1-TRIBUTYLSTANNANE(66680-86-2)

Safety Data

• Hazard Codes: T
• Hazardous Substances Data: 66680-86-2(Hazardous Substances Data)

Usage

Uses

2-Methylpropene-1-tributylstannane is used in the preparation of serrulatane and amphilectane diterpenes.

InChI:InChI=1/C4H7.3C4H9.Sn/c1-4(2)3;3*1-3-4-2;/h1H,2-3H3;3*1,3-4H2,2H3;/rC16H34Sn/c1-6-9-12-17(13-10-7-2,14-11-8-3)15-16(4)5/h15H,6-14H2,1-5H3

Upstream product

• 27262-82-4 tributylstannylmagnesium chloride 
• 75-36-5 acetyl chloride 
• 78-84-2 isobutyraldehyde 
• 3017-69-4 2-methyl-1-propenylbromide 
• 1461-22-9 tributyltin chloride 
• 7439-95-4 magnesium 
• 106-93-4 ethylene dibromide 
• 937-63-3 p-Tolyl chlorothionoformate 
• 136052-50-1 (R)-1-(tributylstannyl)-2-methyl-1-propanol 

Downstream Products

• 133986-12-6 1-(4-tertbutylcyclohex-1-en-1-yl)-3-methylbut-2-en-1-one 
• 66262-15-5 2-(2-methyl-1-propen-1-yl)-2-cyclohexen-1-one 
• 38142-58-4 (+/-)-ar-turmerone 
• 35814-42-7 1-cyclohexylidene-4-methylpent-3-en-2-one 
• 131111-05-2 (6R,7R)-3-(2-Methyl-propenyl)-8-oxo-7-phenylacetylamino-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid 4-methoxy-benzyl ester 
• 123266-31-9 (6R,7S)-3-(2-Methyl-propenyl)-8-oxo-7-(2-phenoxy-acetylamino)-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester 
• 122576-99-2 (6R,7R)-3-(2-Methyl-propenyl)-8-oxo-7-phenylacetylamino-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester 
• 122553-65-5 (6R,7R)-7-[(S)-2-tert-Butoxycarbonylamino-2-(4-hydroxy-phenyl)-acetylamino]-3-(3-methyl-but-2-enyl)-8-oxo-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester 
• 122576-99-2 (6R,7R)-3-(2-Methyl-propenyl)-8-oxo-7-phenylacetylamino-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester 
• 123266-40-0 (6R,7S)-7-((R)-2-tert-Butoxycarbonylamino-2-phenyl-acetylamino)-3-(2-methyl-propenyl)-8-oxo-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester 
• 81925-60-2 3-Methyl-2-(2-methyl-propenyl)-cyclohex-2-enone 
• 140710-01-6 5-Methyl-3-[1-phenyl-meth-(E)-ylidene]-hex-4-en-2-one 
• 139048-05-8 1-Methyl-4-((R)-(E)-4-methyl-penta-1,3-diene-1-sulfinyl)-benzene 
• 502-33-0 (Z)-ocimenone 

Relevant articles and documents

Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control

A stereogenic center, placed at an exocyclic location next to a chiral carbon in a ring to which it is attached, is a ubiquitous structural motif seen in many bioactive natural products, including di- and triterpenes and steroids. Installation of these ce

5-SUBSTITUTED-PYRAZINE OR PYRIDINE GLUCOKINASE ACTIVATORS

The present invention provides a compound according to formula (I) where the substituent designations are provided in the specification. Pharmaceutical compositions comprising a compound according to formula (I) are also provided, said compounds being glucokinase activators which are useful in the treatment of type II diabetes.