66897-25-4

Basic information

• Product Name: 4-methoxy-N-(prop-2-en-1-yl)benzamide
• Synonyms: benzamide, 4-methoxy-N-2-propen-1-yl-; N-Allyl-4-methoxybenzamide
• CAS NO: 66897-25-4
• Molecular Formula: C₁₁H₁₃NO₂
• Molecular Weight: 191.2264
• Mol File: 66897-25-4.mol
• Article Data: 22

Chemical Properties

• Boiling Point: 348.9°C at 760 mmHg
• Flash Point: 164.8°C
• Density: 1.051g/cm³
• Vapor Pressure: 4.88E-05mmHg at 25°C
• Refractive Index: 1.522
• CAS DataBase Reference: 4-methoxy-N-(prop-2-en-1-yl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy-N-(prop-2-en-1-yl)benzamide(66897-25-4)
• EPA Substance Registry System: 4-methoxy-N-(prop-2-en-1-yl)benzamide(66897-25-4)

Safety Data

• Hazardous Substances Data: 66897-25-4(Hazardous Substances Data)

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 107-11-9 1-amino-2-propene 
• 30364-57-9 4-methoxybenzoic acid 2,5-dioxo-1-pyrrolidinyl ester 
• 696-62-8 para-iodoanisole 
• 15226-74-1 dicobalt octacarbonyl 
• 104-93-8 p-methylanizole 
• 100-09-4 4-methoxybenzoic acid 
• 13939-06-5 molybdenum hexacarbonyl 

Downstream Products

• 99859-27-5 5-(bromomethyl)-2-(4-methoxyphenyl)-4,5-dihydrooxazole 
• 100126-18-9 4-methoxy-benzoic acid-(2,3-dibromo-propylamide) 
• 66896-89-7 N-Allyl-N-(4-methoxy-benzoyl)-benzenesulfonamide 
• 139583-91-8 2-methyl-4-methoxybenzamide 
• 255395-92-7 4-methoxy-N-propanoyl-N-prop-2-enylbenzamide 
• 3424-93-9 4-methoxyphenylacetamide 
• 4995-12-4 2-(4-methoxyphenyl)-1H-pyrrole 
• 319483-27-7 N-((Z)-1-{[(tert-butyl)dimethylsilyl]oxy}prop-1-enyl)-4-methoxy-N-prop-2-enylbenzamide 
• 1433416-60-4 (2-(4-methoxyphenyl)-4,5-dihydrooxazol-5-yl)methyl acetate 
• 1450916-45-6 (E)-4-methoxy-N-(prop-1-en-1-yl)benzamide 
• 72432-10-1 aniracetam 
• 23429-02-9 5-methyl-2-(4-methoxylphenyl)-4,5-dihydrooxazole 
• 105-13-5 4-Methoxybenzyl alcohol 

Relevant articles and documents

Electrochemical oxidative cyclization of: N -allylcarboxamides: Efficient synthesis of halogenated oxazolines

Herein, we reported an efficient and sustainable intramolecular electrochemical cyclization of N-allylcarboxamides for the synthesis of various halogenated oxazolines. This method was conducted in a simple undivided cell by employing lithium halogen salts

A Next-Generation Air-Stable Palladium(I) Dimer Enables Olefin Migration and Selective C?C Coupling in Air

We report a new air-stable PdI dimer, [Pd(μ-I)(PCy2tBu)]2, which triggers E-selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C?C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C?Br, C?OTf/OFs, and C?Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C?OTf.

Electrochemical Chalcogenation of β,γ-Unsaturated Amides and Oximes to Corresponding Oxazolines and Isoxazolines

The current report represents a transition-metal-free synthesis of oxazoline and isoxazoline derivatives by a tandem electro-oxidative chalcogenation-cyclization process. Both C?Se and C?S bond-forming protocols were developed without using any external oxidant and the reaction was performed at room temperature, open to the air. Using this methodology, 29 substituted oxazoline and 16 substituted isoxazoline derivatives were synthesized with up to 91% isolated yield. (Figure presented.).