6743-85-7Relevant articles and documents
Simple synthesis of phenylpropenoid β-D-glucopyranoside congeners based on Mizoroki-Heck type reaction of organoboron reagents
Kishida, Masashi,Akita, Hiroyuki
, p. 4123 - 4125 (2007/10/03)
Palladium(II)-catalyzed carbon-carbon bond formation between allyl 2,3,4,6-tetra-O-acetyl-β-d-glucopyranoside (3) and phenylboronic acid congeners gave the phenylpropenoid 2,3,4,6-tetra-O-acetyl-β-d- glucopyranoside (4a-f) in good yield. Among them, compounds 4a-c were converted to the naturally occurring phenylpropenoid β-d-glucopyranoside analogues (1a-c).
Chemoenzymatic syntheses of naturally occurring β-glucosides
Akita, Hiroyuki,Kurashima, Katsumi,Nakamura, Takuya,Kato, Keisuke
, p. 2429 - 2439 (2007/10/03)
Enzymatic glycosidation of the various kinds of primary alcohols 5, 7, 9, 11, 13 and 15 and 4-nitrophenyl-β-D-glucopyranoside 4 using β- glucosidase from almonds gave stereoselectively β-D-glucosides 6, 8, 10, 12, 14 and 16 including the naturally occurring β-glucosides in moderate yield. Among them, the β-glucosides 6, 8 and 10 were converted to the cyanoglycosides, rhodiocyanoside A 20a, osmaronin 24a and sutherlandin 29, respectively.