67546-62-7Relevant articles and documents
Iodocyclization of hydroxylamine derivatives based on the control of oxidative aromatization leading to 2,5-dihydroisoxazoles and isoxazoles
Okitsu, Takashi,Sato, Kana,Potewar, Taterao M.,Wada, Akimori
experimental part, p. 3438 - 3449 (2011/06/26)
An efficient method for the synthesis of 2,5-dihydroisoxazoles and isoxazoles using iodocyclization of N-alkoxycarbonyl O-propargylic hydroxylamines has been developed. 2,5-Dihydro-4-iodoisoxazole underwent the cross-coupling reactions without aromatization to afford polyfunctionalized 2,5-dihydroisoxazoles. This process was applied to the preparation of valdecoxib and its 2,5-dihydro-derivative.
Vinylallenes. Part 11. Evidence for the Formation of an Organometallic Species in the Reaction of a Tosylate with an LiAlH4-CuBr Reagent
Delbecq, Francoise,Baudouy, Rene,Gore, Jacques
, p. 971 - 979 (2007/10/02)
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