67829-50-9Relevant articles and documents
A Method for Identifying and Developing Functional Group Tolerant Catalytic Reactions: Application to the Buchwald-Hartwig Amination
Richardson, Jeffery,Ruble, J. Craig,Love, Elizabeth A.,Berritt, Simon
, p. 3741 - 3750 (2017)
Transition-metal catalysis has revolutionized organic synthesis, but difficulties can often be encountered when applied to highly functionalized molecules, such as pharmaceuticals and their precursors. This results in discovery collections that are enrich
Rh[III]-catalyzed direct C-H amination using N -chloroamines at room temperature
Grohmann, Christoph,Wang, Honggen,Glorius, Frank
, p. 656 - 659 (2012/03/08)
An efficient Rh(III)-catalyzed direct C-H amination of N-pivaloyloxy benzamides with N-chloroamines proceeding at room temperature was achieved. The versatile directing group allows for selective mono- and diamination and can be readily converted to give valuable benzamide or aminoaniline derivatives. Mechanistic studies have been carried out to elucidate the reaction pathway.
Cyclodehydrogenation of aniline derivatives carrying carboxamide or urea functions
Moehrle,Hemmerling
, p. 586 - 594 (2007/10/04)
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