67899-60-9

Basic information

• Product Name: cis-1,2,3,4-tetrahydro-2,3-diphenylpyrido<3,4-b>pyrazine
• CAS NO: 67899-60-9
• Molecular Weight: 287.364
• Mol File: 67899-60-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-1,2,3,4-tetrahydro-2,3-diphenylpyrido<3,4-b>pyrazine(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1,2,3,4-tetrahydro-2,3-diphenylpyrido<3,4-b>pyrazine(67899-60-9)
• EPA Substance Registry System: cis-1,2,3,4-tetrahydro-2,3-diphenylpyrido<3,4-b>pyrazine(67899-60-9)

Safety Data

• Hazardous Substances Data: 67899-60-9(Hazardous Substances Data)

Upstream product

• 134-81-6 benzil 
• 67899-59-6 2,3-diphenylpyrido<3,4-b>pyrazine 
• 54-96-6 3,4-diaminopyridine 

Relevant articles and documents

Modular design of pyridine-based acyl-transfer catalysts

Derivatives of 3,4-diaminopyridine have been synthesized and studied as catalysts for acyl-transfer reactions. The design of these catalysts is guided by the stability of their acetyl intermediates as determined through theoretical calculations at the B3LYP/6-311 + G(d,p)//B3LYP/6-31G(d) level of theory. The most promising catalysts have been synthesized through a three- to five-step synthesis starting from 3,4-diaminopyridine. The catalytic activity has been determined for the acylation of 1-ethynylcyclohexanol with acetic anhydride at 23°C and with isobutyric anhydride at 40°C. For both reactions, the catalytic activity depends dramatically on the substitution pattern of the diaminopyridines. Best results are obtained with catalysts containing alkyl substituents at both amine nitrogens. Georg Thieme Verlag Stuttgart.