67945-96-4

Basic information

• Product Name: Benzene, 1,1'-(1-ethenyl-1,2-ethenediyl)bis-, (Z)-
• CAS NO: 67945-96-4
• Molecular Formula: C16H14
• Molecular Weight: 206.287
• Mol File: 67945-96-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-ethenyl-1,2-ethenediyl)bis-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-ethenyl-1,2-ethenediyl)bis-, (Z)-(67945-96-4)
• EPA Substance Registry System: Benzene, 1,1'-(1-ethenyl-1,2-ethenediyl)bis-, (Z)-(67945-96-4)

Safety Data

• Hazardous Substances Data: 67945-96-4(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 13702-35-7 (E)-2,3-diphenyl-propenal 
• 13633-26-6 4-phenylbut-1-en-3-yne 
• 131437-38-2 (Z)-3,4-diphenylbut-3-en-2-ol 
• 71321-00-1 trimethyl(phenyl)(1-phenyl-1,2-propadienyl)silane 
• 100-52-7 benzaldehyde 
• 109-92-2 ethyl vinyl ether 
• 501-65-5 diphenyl acetylene 
• 83564-70-9 4-phenylbuta-2,3-dien-1-ol 
• 98-80-6 phenylboronic acid 
• 67-68-5 dimethyl sulfoxide 
• 91-48-5 (E)-2,3-diphenylpropenoic acid 
• 22835-64-9 α-phenylcinnamyl alcohol 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 67946-21-8 2,5,6-triphenyl-3,6-dihydro-2H-[1,2]oxazine 
• 67946-23-0 2-(4-methoxy-phenyl)-5,6-diphenyl-3,6-dihydro-2H-[1,2]oxazine 
• 67946-20-7 2-(4-chloro-phenyl)-5,6-diphenyl-3,6-dihydro-2H-[1,2]oxazine 
• 67946-22-9 5,6-diphenyl-2-p-tolyl-3,6-dihydro-2H-[1,2]oxazine 

Relevant articles and documents

Reactions of Styrylmalonates with Aromatic Aldehydes: Detailed Synthetic and Mechanistic Studies

Reactions of styrylmalonates with aromatic aldehydes in the presence of Lewis and Br?nsted acids and their regularities have been studied in detail. Approaches to the synthesis of various polysubstituted 5,6-dihydropyran-2-ones, indenes, aryl-containing d

Nickel-catalyzed dehydrogenative [4 + 2] cycloaddition of 1,3-dienes with nitriles

Pyridines, which comprise one of the most important classes of the six-membered heterocyclic compounds, are widely distributed in nature, and the transition-metal-catalyzed [2 + 2 + 2] cycloaddition reaction of two alkynes and a nitrile is one of the most powerful methods for preparing versatile, highly substituted pyridine derivatives. However, the lack of chemo- and regioselectivity is still a crucial issue associated with fully intermolecular [2 + 2 + 2] cycloaddition. The present study developed the Ni(0)-catalyzed intermolecular dehydrogenative [4 + 2] cycloaddition reaction of 1,3-butadienes with nitriles to give a variety of pyridines regioselectively.

Titanocene(II)-promoted cross-coupling of unsaturated compounds

Vinyl pivalate in the presence of the titanocene(II) reagent Cp 2Ti[P(OEt)3]2 reacts both with nonpolar C≡C triple bonds and with polar C=O double bonds, to produce conjugated dienes and allylic alcohols, respectively. Similar alkenylation also takes place when (Z)-alkenyl sulfones are treated with alkynes and carbonyl compounds. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.