68326-56-7Relevant articles and documents
Highly enantiomeric purity conversion of α-sulfinyl oximes and α-sulfinyl hydrazones to the corresponding β-keto sulfoxides with butyltriphenylphosphonium periodate (BUTPPPI)
Hajipour,Ruoho
, p. 2653 - 2657 (2007/10/03)
Butyltriphenylphosphonium periodate (Ph3P+BuIO 4-)1 is readily prepared as a white solid from butyltriphenylphosphonium chloride, performs conversion of α-sulfinyl oximes (2) and α-sulfinyl hydrazones (4) to the
Highly Diastereoselective Hydrocyanation of β-Keto Sulfoxides: Synthesis of Enantiomerically Pure Cyanohydrin Derivatives
Ruano, Jose L. Garcia,Castro, Ana M. Martin,Rodriguez, Jesus H.
, p. 7235 - 7241 (2007/10/02)
The reactions of chiral β-keto sulfoxides, R1-CO-CHR2-SOTol (R1 = Me, n-Pr, i-Pr, t-Bu, Ph; R2 = H, Me) with Et2AlCN yield the corresponding sulfinyl cyanohydrins with high yields (85-96percent) and de (>96perce
Stereospecific Synthesis of Chiral α-Sulfinylhydrazones
Banfi, Luca,Colombo, Lino,Gennari, Cesare,Annunziata, Rita,Cozzi, Franco
, p. 829 - 831 (2007/10/02)
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